• | Amending WAC 173-201A-240 Toxic substances, specifically updating aquatic life toxics criteria in Table 240 and footnotes. |
• | Minor, nonsubstantive edits to rule language in WAC 173-201A-240 to correct typographical, calculation, and formatting errors, and to cite federal regulations for human health criteria where they apply for Clean Water Act (CWA) purposes. |
• | Aldrin (freshwater and saltwater acute). |
• | Arsenic (freshwater acute and chronic and saltwater acute and chronic). |
• | Cadmium (freshwater acute and chronic and saltwater acute and chronic). |
• | Chromium III (freshwater acute and chronic). |
• | Chromium VI (freshwater acute and chronic). |
• | Copper (freshwater acute and chronic). |
• | Cyanide (freshwater acute and chronic). |
• | Dieldrin (freshwater acute and chronic). |
• | Endrin (freshwater acute and chronic). |
• | Gamma-BHC (freshwater acute). |
• | Mercury (freshwater acute). |
• | Nickel (freshwater acute and chronic). |
• | Pentachlorophenol (freshwater acute and chronic and saltwater chronic). |
• | Selenium (freshwater acute and chronic). |
• | Silver (freshwater and saltwater acute). |
• | Zinc (freshwater acute and chronic). |
• | 6PPD-quinone (freshwater acute). |
• | Aluminum (freshwater acute and chronic). |
• | Acrolein (freshwater acute and chronic). |
• | Carbaryl (freshwater acute and chronic and saltwater acute). |
• | Demeton (freshwater and saltwater chronic). |
• | Diazinon (freshwater acute and chronic and saltwater acute and chronic). |
• | Guthion (freshwater and saltwater chronic). |
• | Malathion (freshwater and saltwater chronic). |
• | Methoxychlor (freshwater and saltwater chronic). |
• | Mirex (freshwater and saltwater chronic). |
• | Nonylphenol (freshwater acute and chronic and saltwater acute and chronic). |
• | PFOS (freshwater acute and chronic and saltwater acute). |
• | PFOA (freshwater acute and chronic and saltwater acute). |
• | Silver (freshwater and saltwater chronic). |
• | Tributyltin (freshwater acute and chronic and saltwater acute and chronic). |
• | Updating different classes (such as metals and organics) of toxic substances in staggered rule makings. |
• | Rule makings for different groups of toxic substances based on highest priority. |
• | A review and update of all necessary criteria in a single rule making. |
• | Compliance requirements of the proposed rule. |
• | Results of the analysis of relative compliance cost burden. |
• | Consideration of lost sales or revenue. |
• | Cost-mitigating action taken by ecology, if required. |
• | Small business and local government consultation. |
• | Industries likely impacted by the proposed rule. |
• | Expected net impact on jobs statewide. |
• | Ecology receiving the permit application. |
• | Review of the application for completeness and accuracy. |
• | Derivation of applicable technology-based effluent limits. |
• | Determination of whether effluent will cause, or have reasonable potential to cause or contribute to, violation of water quality standards. |
• | If yes, derivation of water quality-based effluent limits. |
• | Determination of monitoring requirements and other special conditions. |
• | Review process for the draft or proposed permit. |
• | Issuance of the final permit decision. |
• | Arsenic (all). |
• | Cadmium (all). |
• | Chromium III (freshwater acute and chronic). |
• | Chromium VI (freshwater acute and chronic). |
• | Copper (freshwater acute and chronic). |
• | Cyanide (freshwater acute and chronic). |
• | Dieldrin (freshwater acute and chronic). |
• | Endrin (freshwater acute and chronic). |
• | Gamma-BHC (freshwater acute). |
• | Mercury (freshwater acute). |
• | Nickel (freshwater acute and chronic). |
• | Pentachlorophenol (freshwater acute and chronic and saltwater chronic). |
• | Selenium (freshwater acute and chronic). |
• | Silver (freshwater and saltwater acute). |
• | Zinc (freshwater acute and chronic). |
• | Aldrin (freshwater and saltwater acute). |
• | 6PPD-quinone (freshwater acute). |
• | Aluminum (freshwater acute and chronic). |
• | Acrolein (freshwater acute and chronic). |
• | Carbaryl (freshwater acute and chronic and saltwater acute). |
• | Demeton (freshwater and saltwater chronic). |
• | Diazinon (all). |
• | Guthion (freshwater and saltwater chronic). |
• | Malathion (freshwater and saltwater chronic). |
• | Methoxychlor (freshwater and saltwater chronic). |
• | Mirex (freshwater and saltwater chronic). |
• | Nonylphenol (all). |
• | PFOS (freshwater acute and chronic and saltwater acute). |
• | PFOA (freshwater acute and chronic and saltwater acute). |
• | Silver (freshwater and saltwater chronic). |
• | Tributyltin (all). |
• | Make minor, nonsubstantive edits to rule language in WAC 173-201A-240 to correct typographical, calculation, and formatting errors. |
• | Arsenic (all). |
• | Cadmium (freshwater acute and chronic). |
• | Copper. |
• | Chromium VI (freshwater acute and chronic). |
• | Nickel (freshwater acute and chronic). |
• | Silver (freshwater acute and chronic). |
• | Zinc (freshwater acute and chronic). |
• | 6PPD-quinone (freshwater acute). |
• | Cyanide (freshwater acute and chronic). |
• | Pentachlorophenol (all). |
• | PFOS (freshwater acute and chronic and saltwater acute). |
• | PFOA (freshwater acute and chronic and saltwater acute). |
• | Minor, nonsubstantive edits to rule language in WAC 173-201A-240 to correct typographical, calculation, and formatting errors associated with the list above. |
Action Level | Low-Cost Estimate | High-Cost Estimate | ||
1 | $12,304 | $24,608 | ||
2 | $173,531 | $173,531 | ||
3 | $14,250,000 | $42,750,000 | ||
Lab Costs | $3,128,218 | $9,428,912 | ||
Total | $17,564,053 | $52,377,051 |
1 | https://www.dnb.com/. |
Type of cost (or total cost) | Small Businesses | Largest 10% of Businesses | ||
Average employment | 20 | 4,638 | ||
Compliance costs per entity (low) | $8,005 | $89,947 | ||
Compliance costs per entity (high) | $23,897 | $268,593 | ||
Cost per employee (low) | $410 | $19 | ||
Cost per employee (high) | $1,223 | $58 |
• | Are legal and feasible. |
• | Meet the goals and objectives of the authorizing statute. |
• | Are within the scope of this rule making. |
NAICS Code | Description |
111x | Crop Production |
112x | Animal Production and Aquaculture |
113x | Forestry and Logging |
114x | Fishing, Hunting and Trapping |
221x | Utilities |
236x | Construction of Buildings |
237x | Heavy and Civil Engineering Construction |
238x | Specialty Trade Contractors |
311x | Food Manufacturing |
312x | Beverage and Tobacco Product Manufacturing |
314x | Textile Product Mills |
321x | Wood Product Manufacturing |
322x | Paper Manufacturing |
324x | Petroleum and Coal Products Manufacturing |
325x | Chemical Manufacturing |
326x | Plastics and Rubber Products Manufacturing |
327x | Nonmetallic Mineral Product Manufacturing |
331x | Primary Metal Manufacturing |
332x | Fabricated Metal Product Manufacturing |
333x | Machinery Manufacturing |
334x | Computer and Electronic Product Manufacturing |
335x | Electrical Equipment, Appliance, and Component Manufacturing |
336x | Transportation Equipment Manufacturing |
337x | Furniture and Related Product Manufacturing |
339x | Miscellaneous Manufacturing |
423x | Merchant Wholesalers, Durable Goods |
424x | Merchant Wholesalers, Nondurable Goods |
441x | Motor Vehicle and Parts Dealers |
444x | Building Material and Garden Equipment and Supplies Dealers |
445x | Food and Beverage Retailers |
455x | General Merchandise Retailers |
457x | Gasoline Stations and Fuel Dealers |
458x | Clothing, Clothing Accessories, Shoe, and Jewelry Retailers |
459x | Sporting Goods, Hobby, Musical Instrument, Book, and Miscellaneous Retailers |
481x | Air Transportation |
482x | Rail Transportation |
484x | Truck Transportation |
485x | Transit and Ground Passenger Transportation |
488x | Support Activities for Transportation |
492x | Couriers and Messengers |
493x | Warehousing and Storage |
522x | Credit Intermediation and Related Activities |
524x | Insurance Carriers and Related Activities |
531x | Real Estate |
532x | Rental and Leasing Services |
533x | Lessors of Nonfinancial Intangible Assets (except Copyrighted Works) |
541x | Professional, Scientific, and Technical Services |
561x | Administrative and Support Services |
562x | Waste Management and Remediation Services |
621x | Ambulatory Health Care Services |
624x | Social Assistance |
713x | Amusement, Gambling, and Recreation Industries |
722x | Food Services and Drinking Places |
811x | Repair and Maintenance |
928x | National Security and International Affairs |
Industry | 2030 (low) | 2030 (high) | 2045 (low) | 2045 (high) | ||
Whole state | -23 | -69 | -1 | -2 | ||
Retail trade | -3 | -9 | 0 | 0 | ||
Construction | -3 | -9 | 0 | 0 | ||
Wholesale trade | -2 | -7 | 0 | 0 | ||
Real estate | -2 | -7 | 0 | 0 | ||
State and local government | -1 | -3 | 0 | 0 |
Industry | 2030 Jobs Impact (low) | 2030 Jobs Impact (high) | 2045 Jobs Impact (low) | 2045 Jobs Impact (high) | ||
Whole state | -113 | -337 | -2 | -6 | ||
Construction | -20 | -60 | 0 | 1 | ||
Retail trade | -13 | -39 | 0 | 0 | ||
State and local government | -6 | -19 | 0 | -1 | ||
Wholesale trade | -6 | -17 | 0 | 0 | ||
Real estate | -6 | -17 | 0 | 0 |
((Compound/Chemical | Chemical Abstracts Service (CAS)# | Category | Aquatic Life Criteria - Freshwater | Aquatic Life Criteria - Marine Water | Human Health Criteria for Consumption of: | |||
Acute | Chronic | Acute | Chronic | Water & Organisms | Organisms Only | |||
Metals: | ||||||||
Antimony | 7440360 | Metals, cyanide, and total phenols | - | - | - | - | 12 | 180 |
Arsenic | 7440382 | Metals, cyanide, and total phenols | 360.0 (c,dd) | 190.0 (d,dd) | 69.0 (c,ll,dd) | 36.0 (d,cc,ll,dd) | 10 (A) | 10 (A) |
Asbestos | 1332214 | Toxic pollutants and hazardous substances | - | - | - | - | 7,000,000 fibers/L (C) | - |
Beryllium | 7440417 | Metals, cyanide, and total phenols | - | - | - | - | - | - |
Cadmium | 7440439 | Metals, cyanide, and total phenols | (i,c,dd) | (j,d,dd) | 42.0 (c,dd) | 9.3 (d,dd) | - | - |
Chromium (III) | 16065831 | Metals, cyanide, and total phenols | (m,c,gg) | (n,d,gg) | - | - | - | - |
Chromium (VI) | 18540299 | Metals, cyanide, and total phenols | 15.0 (c,l,ii,dd) | 10.0 (d,jj,dd) | 1,100.0 (c,l,ll,dd) | 50.0 (d,ll,dd) | - | - |
Copper | 7440508 | Metals, cyanide, and total phenols | (o,c,dd) | (p,d,dd) | 4.8 (c,ll,dd) | 3.1 (d,ll,dd) | 1,300 (C) | - |
Lead | 7439921 | Metals, cyanide, and total phenols | (q,c,dd) | (r,d,dd) | 210.0 (c,ll,dd) | 8.1 (d,ll,dd) | - | - |
Mercury | 7439976 | Metals, cyanide, and total phenols | 2.1 (c,kk,dd) | 0.012 (d,ff,s) | 1.8 (c,ll,dd) | 0.025 (d,ff,s) | (G) | (G) |
Methylmercury | 22967926 | Nonconventional | - | - | - | - | - | - |
Nickel | 7440020 | Metals, cyanide, and total phenols | (t,c,dd) | (u,d,dd) | 74.0 (c,ll,dd) | 8.2 (d,ll,dd) | 150 | 190 |
Selenium | 7782492 | Metals, cyanide, and total phenols | 20.0 (c,ff) | 5.0 (d,ff) | 290 (c,ll,dd) | 71.0 (d,x,ll,dd) | 120 | 480 |
Silver | 7440224 | Metals, cyanide, and total phenols | (y,a,dd) | - | 1.9 (a,ll,dd) | - | - | - |
Thallium | 7440280 | Metals, cyanide, and total phenols | - | - | - | - | 0.24 | 0.27 |
Zinc | 7440666 | Metals, cyanide, and total phenols | (aa,c,dd) | (bb,d,dd) | 90.0 (c,ll,dd) | 81.0 (d,ll,dd) | 2,300 | 2,900 |
Other chemicals: | ||||||||
1,1,1-Trichloroethane | 71556 | Volatile | - | - | - | - | 47,000 | 160,000 |
1,1,2,2-Tetrachloroethane | 79345 | Volatile | - | - | - | - | 0.12 (B) | 0.46 (B) |
1,1,2-Trichloroethane | 79005 | Volatile | - | - | - | - | 0.44 (B) | 1.8 (B) |
1,1-Dichloroethane | 75343 | Volatile | - | - | - | - | - | - |
1,1-Dichloroethylene | 75354 | Volatile | - | - | - | - | 1200 | 4100 |
1,2,4-Trichlorobenzene | 120821 | Base/neutral compounds | - | - | - | - | 0.12 (B) | 0.14 (B) |
1,2-Dichlorobenzene | 95501 | Volatile | - | - | - | - | 2000 | 2500 |
1,2-Dichloroethane | 107062 | Volatile | - | - | - | - | 9.3 (B) | 120 (B) |
1,2-Dichloropropane | 78875 | Volatile | - | - | - | - | 0.71 (B) | 3.1 (B) |
1,3-Dichloropropene | 542756 | Volatile | - | - | - | - | 0.24 (B) | 2 (B) |
1,2-Diphenylhydrazine | 122667 | Base/neutral compounds | - | - | - | - | 0.015 (B) | 0.023 (B) |
1,2-Trans-Dichloroethylene | 156605 | Volatile | - | - | - | - | 600 | 5,800 |
1,3-Dichlorobenzene | 541731 | Volatile | - | - | - | - | 13 | 16 |
1,4-Dichlorobenzene | 106467 | Volatile | - | - | - | - | 460 | 580 |
2,3,7,8-TCDD (Dioxin) | 1746016 | Dioxin | - | - | - | - | 0.000000064 | 0.000000064 |
2,4,6-Trichlorophenol | 88062 | Acid compounds | - | - | - | - | 0.25 (B) | 0.28 (B) |
2,4-Dichlorophenol | 120832 | Acid compounds | - | - | - | - | 25 | 34 |
2,4-Dimethylphenol | 105679 | Acid compounds | - | - | - | - | 85 | 97 |
2,4-Dinitrophenol | 51285 | Acid compounds | - | - | - | - | 60 | 610 |
2,4-Dinitrotoluene | 121142 | Base/neutral compounds | - | - | - | - | 0.039 (B) | 0.18 (B) |
2,6-Dinitrotoluene | 606202 | Base/neutral compounds | - | - | - | - | - | - |
2-Chloroethyvinyl Ether | 110758 | Volatile | - | - | - | - | - | - |
2-Chloronaphthalene | 91587 | Base/neutral compounds | - | - | - | - | 170 | 180 |
2-Chlorophenol | 95578 | Acid compounds | - | - | - | - | 15 | 17 |
2-Methyl-4,6-Dinitrophenol (4,6-dinitro-o-cresol) | 534521 | Acid compounds | - | - | - | - | 7.1 | 25 |
2-Nitrophenol | 88755 | Acid compounds | - | - | - | - | - | - |
3,3'-Dichlorobenzidine | 91941 | Base/neutral compounds | - | - | - | - | 0.0031 (B) | 0.0033 (B) |
3-Methyl-4-Chlorophenol (parachlorometa cresol) | 59507 | Acid compounds | - | - | - | - | 36 | 36 |
4,4'-DDD | 72548 | Pesticides/PCBs | - | - | - | - | 0.000036 (B) | 0.000036 (B) |
4,4'-DDE | 72559 | Pesticides/PCBs | - | - | - | - | 0.000051 (B) | 0.000051 (B) |
4,4'-DDT | 50293 | Pesticides/PCBs | - | - | - | - | 0.000025 (B) | 0.000025 (B) |
4,4'-DDT(and metabolites) | Pesticides/PCBs | 1.1 (a) | 0.001 (b) | 0.13 (a) | 0.001 (b) | - | - | |
4-Bromophenyl Phenyl Ether | 101553 | Base/neutral compounds | - | - | - | - | - | - |
4-Chorophenyl Phenyl Ether | 7005723 | Base/neutral compounds | - | - | - | - | - | - |
4-Nitrophenol | 100027 | Acid compounds | - | - | - | - | - | - |
Acenaphthene | 83329 | Base/neutral compounds | - | - | - | - | 110 | 110 |
Acenaphthylene | 208968 | Base/neutral compounds | - | - | - | - | - | - |
Acrolein | 107028 | Volatile | - | - | - | - | 1.0 | 1.1 |
Acrylonitrile | 107131 | Volatile | - | - | - | - | 0.019 (B) | 0.028 (B) |
Aldrin | 309002 | Pesticides/PCBs | 2.5 (a,e) | 0.0019 (b,e) | 0.71 (a,e) | 0.0019 (b,e) | 0.0000057 (B) | 0.0000058 (B) |
alpha-BHC | 319846 | Pesticides/PCBs | - | - | - | - | 0.0005 (B) | 0.00056 (B) |
alpha-Endosulfan | 959988 | Pesticides/PCBs | - | - | - | - | 9.7 | 10 |
Anthracene | 120127 | Base/neutral compounds | - | - | - | - | 3,100 | 4,600 |
Benzene | 71432 | Volatile | - | - | - | - | 0.44 (B) | 1.6 (B) |
Benzidine | 92875 | Base/neutral compounds | - | - | - | - | 0.00002 (B) | 0.000023 (B) |
Benzo(a) Anthracene | 56553 | Base/neutral compounds | - | - | - | - | 0.014 (B) | 0.021 (B) |
Benzo(a) Pyrene | 50328 | Base/neutral compounds | - | - | - | - | 0.0014 (B) | 0.0021 (B) |
Benzo(b) Fluoranthene | 205992 | Base/neutral compounds | - | - | - | - | 0.014 (B) | 0.021 (B) |
Benzo(hi) Propylene | 191242 | Base/neutral compounds | - | - | - | - | - | - |
Benzo(k) Fluoranthene | 207089 | Base/neutral compounds | - | - | - | - | 0.014 (B) | 0.21 (B) |
beta-THC | 319857 | Pesticides/PCBs | - | - | - | - | 0.0018 (B) | 0.002 (B) |
alpha-Endosulfan | 33213659 | Pesticides/PCBs | - | - | - | - | 9.7 | 10 |
Bis(2-Chloroethoxy) Methane | 111911 | Base/neutral compounds | - | - | - | - | - | - |
Bis(2-Chloroethyl) Ether | 111444 | Base/neutral compounds | - | - | - | - | 0.02 (B) | 0.06 (B) |
Bis(2-Chloroisopropyl) Ether | 39638329 | Base/neutral compounds | - | - | - | - | - | - |
Bis(2-Ethylhexyl) Phthalate | 117817 | Base/neutral compounds | - | - | - | - | 0.23 (B) | 0.25 (B) |
Bromoform | 75252 | Volatile | - | - | - | - | 5.8 (B) | 27 (B) |
Butylbenzyl Phthalate | 85687 | Base/neutral compounds | - | - | - | - | 0.56 (B) | 0.58 (B) |
Carbon Tetrachloride | 56235 | Volatile | - | - | - | - | 0.2 (B) | 0.35 (B) |
Chlordane | 57749 | Pesticides/PCBs | 2.4 (a) | 0.0043 (b) | 0.09 (a) | 0.004 (b) | 0.000093 (B) | 0.000093 (B) |
Chlorobenzene | 108907 | Volatile | - | - | - | - | 380 | 890 |
Chlorodibromomethane | 124481 | Volatile | - | - | - | - | 0.65 (B) | 3 (B) |
Chloroethane | 75003 | Volatile | - | - | - | - | - | - |
Chloroform | 67663 | Volatile | - | - | - | - | 260 | 1200 |
Chrysene | 218019 | Base/neutral compounds | - | - | - | - | 1.4 (B) | 2.1 (B) |
Cyanide | 57125 | Metals, cyanide, and total phenols | 22.0 (c,ee) | 5.2 (d,ee) | 1.0 (c,mm,ee) | (d,mm,ee) | 19 (D) | 270 (D) |
delta-BHC | 319868 | Pesticides/PCBs | - | - | - | - | - | - |
Dibenzo(a,h) Anthracene | 53703 | Base/neutral compounds | - | - | - | - | 0.0014 (B) | 0.0021 (B) |
Dichlorobromomethane | 75274 | Volatile | - | - | - | - | 0.77 (B) | 3.6 (B) |
Dieldrin | 60571 | Pesticides/PCBs | 2.5 (a,e) | 0.0019 (b,e) | 0.71 (a,e) | 0.0019 (b,e) | 0.0000061 (B) | 0.0000061 (B) |
Diethyl Phthalate | 84662 | Base/neutral compounds | - | - | - | - | 4,200 | 5,000 |
Dimethyl Phthalate | 131113 | Base/neutral compounds | - | - | - | - | 92,000 | 130,000 |
Di-n-Butyl Phthalate | 84742 | Base/neutral compounds | - | - | - | - | 450 | 510 |
Di-n-Octyl Phthalate | 117840 | Base/neutral compounds | - | - | - | - | - | - |
Endosulfan | Pesticides/PCBs | 0.22 (a) | 0.056 (b) | 0.034 (a) | 0.0087 (b) | - | - | |
Endosulfan Sulfate | 1031078 | Pesticides/PCBs | - | - | - | - | 9.7 | 10 |
Endrin | 72208 | Pesticides/PCBs | 0.18 (a) | 0.0023 (b) | 0.037 (a) | 0.0023 (b) | 0.034 | 0.035 |
Endrin Aldehyde | 7421934 | Pesticides/PCBs | - | - | - | - | 0.034 | 0.035 |
Ethylbenzene | 100414 | Volatile | - | - | - | - | 200 | 270 |
Fluoranthene | 206440 | Base/neutral compounds | - | - | - | - | 16 | 16 |
Fluorene | 86737 | Base/neutral compounds | - | - | - | - | 420 | 610 |
Hexachlorocyclohexane (gamma-BHC; Lindane) | 58899 | Pesticides/PCBs | 2.0 (a) | 0.08 (b) | 0.16 (a) | - | 15 | 17 |
Heptachlor | 76448 | Pesticides/PCBs | 0.52 (a) | 0.0038 (b) | 0.053 (a) | 0.0036 (b) | 0.0000099 (B) | 0.00001 (B) |
Heptachlor Epoxide | 1024573 | Pesticides/PCBs | - | - | - | - | 0.0000074 (B) | 0.0000074 (B) |
Hexachlorobenzene | 118741 | Base/neutral compounds | - | - | - | - | 0.000051 (B) | 0.000052 (B) |
Hexachlorobutadiene | 87683 | Base/neutral compounds | - | - | - | - | 0.69 (B) | 4.1 (B) |
Hexachlorocyclopentadiene | 77474 | Base/neutral compounds | - | - | - | - | 150 | 630 |
Hexachloroethane | 67721 | Base/neutral compounds | - | - | - | - | 0.11 (B) | 0.13 (B) |
Indeno(1,2,3-cd) Pyrene | 193395 | Base/neutral compounds | - | - | - | - | 0.014 (B) | 0.021 (B) |
Isophorone | 78591 | Base/neutral compounds | - | - | - | - | 27 (B) | 110 (B) |
Methyl Bromide | 74839 | Volatile | - | - | - | - | 520 | 2,400 |
Methyl Chloride | 74873 | Volatile | - | - | - | - | - | - |
Methylene Chloride | 75092 | Volatile | - | - | - | - | 16 (B) | 250 (B) |
Napthalene | 91203 | Base/neutral compounds | - | - | - | - | - | - |
Nitrobenzene | 98953 | Base/neutral compounds | - | - | - | - | 55 | 320 |
N-Nitrosodimethylamine | 62759 | Base/neutral compounds | - | - | - | - | 0.00065 (B) | 0.34 (B) |
N-Nitrosodi-n-Propylamine | 621647 | Base/neutral compounds | - | - | - | - | 0.0044 (B) | 0.058 (B) |
N-Nitrosodiphenylamine | 86306 | Base/neutral compounds | - | - | - | - | 0.62 (B) | 0.69 (B) |
Pentachlorophenol (PCP) | 87865 | Acid compounds | (w,c) | (v,d) | 13.0 (c) | 7.9 (d) | 0.046 (B) | 0.1 (B) |
Phenanthrene | 85018 | Base/neutral compounds | - | - | - | - | - | - |
Phenol | 108952 | Acid compounds | - | - | - | - | 18,000 | 200,000 |
Polychlorinated Biphenyls (PCBs) | Pesticides/PCBs | 2.0 (b) | 0.014 (b) | 10.0 (b) | 0.030 (b) | 0.00017 (E) | 0.00017 (E) | |
Pyrene | 129000 | Base/neutral compounds | - | - | - | - | 310 | 460 |
Tetrachloroethylene | 127184 | Volatile | - | - | - | - | 4.9 (B) | 7.1 (B) |
Toluene | 108883 | Volatile | - | - | - | - | 180 | 410 |
Toxaphene | 8001352 | Pesticides/PCBs | 0.73 (c,z) | 0.0002 (d) | 0.21 (c,z) | 0.0002 (d) | 0.000032 (B) | 0.000032 (B) |
Trichloroethylene | 79016 | Volatile | - | - | - | - | 0.38 (B) | 0.86 (B) |
Vinyl Chloride | 75014 | Volatile | - | - | - | - | 0.02 (B, F) | 0.26 (B, F) |
Ammonia (hh) | Nonconventional | (f,c) | (g,d) | 0.233 (h,c) | 0.035 (h,d) | - | - | |
Chloride (dissolved) (k) | Nonconventional | 860.0 (h,c) | 230.0 (h,d) | - | - | - | - | |
Chlorine (total residual) | Nonconventional | 19.0 (c) | 11.0 (d) | 13.0 (c) | 7.5 (d) | - | - | |
Chlorpyrifos | Toxic pollutants and hazardous substances | 0.083 (c) | 0.041 (d) | 0.011 (c) | 0.0056 (d) | - | - | |
Parathion | Toxic pollutants and hazardous substances | 0.065 (c) | 0.013 (d) | - | - | - | - |
Footnotes for aquatic life criteria in Table 240: | |
a. | An instantaneous concentration not to be exceeded at any time. |
b. | A 24-hour average not to be exceeded. |
c. | A 1-hour average concentration not to be exceeded more than once every three years on the average. |
d. | A 4-day average concentration not to be exceeded more than once every three years on the average. |
e. | Aldrin is metabolically converted to Dieldrin. Therefore, the sum of the Aldrin and Dieldrin concentrations are compared with the Dieldrin criteria. |
f. | Shall not exceed the numerical value in total ammonia nitrogen (mg N/L) given by: |
For salmonids present: | 0.275 | + | 39.0 |
1 + 107.204-pH | 1 + 10pH-7.204 | ||
For salmonids absent: | 0.411 | + | 58.4 |
1 + 107.204-pH | 1 + 10pH-7.204 |
g. | Shall not exceed the numerical concentration calculated as follows: |
Unionized ammonia concentration for waters where salmonid habitat is an existing or designated use: |
0.80 ÷ (FT)(FPH)(RATIO) | ||||
where: | RATIO | = | 13.5; 7.7 ≤ pH ≤ 9 | |
RATIO | = | (20.25 x 10(7.7-pH)) ÷ (1 + 10(7.4-pH)); 6.5 ≤ pH ≤ 7.7 | ||
FT | = | 1.4; 15 ≤ T ≤ 30 | ||
FT | = | 10[0.03(20-T)]; 0 ≤ T ≤ 15 | ||
FPH | = | 1; 8 ≤ pH ≤ 9 | ||
FPH | = | (1 + 10(7.4-pH)) ÷ 1.25; 6.5 ≤ pH ≤ 8.0 |
where: A | = | the greater of either T (temperature in degrees Celsius) or 7. |
where: B | = | the lower of either 2.85, or 1.45 x 100.028 x (25-T). T = temperature in degrees Celsius. |
Applied as a thirty-day average concentration of total ammonia nitrogen (in mg N/L) not to be exceeded more than once every three years on the average. The highest four-day average within the thirty-day period should not exceed 2.5 times the chronic criterion. | |
h. | Measured in milligrams per liter rather than micrograms per liter. |
i. | ≤ (0.944)(e(1.128[ln(hardness)]-3.828)) at hardness = 100. Conversion factor (CF) of 0.944 is hardness dependent. CF is calculated for other hardnesses as follows: CF = 1.136672 - [(ln hardness)(0.041838)]. |
j. | ≤ (0.909)(e(0.7852[ln(hardness)]-3.490)) at hardness = 100. Conversions factor (CF) of 0.909 is hardness dependent. CF is calculated for other hardnesses as follows: CF = 1.101672 - [(ln hardness)(0.041838)]. |
k. | Criterion based on dissolved chloride in association with sodium. This criterion probably will not be adequately protective when the chloride is associated with potassium, calcium, or magnesium, rather than sodium. |
l. | Salinity dependent effects. At low salinity the 1-hour average may not be sufficiently protective. |
m. | ≤ (0.316)(e(0.8190[ ln(hardness)] + 3.688)) |
n. | ≤ (0.860)(e(0.8190[ ln(hardness)] + 1.561)) |
o. | ≤ (0.960)(e(0.9422[ ln(hardness)] - 1.464)) |
p. | ≤ (0.960)(e(0.8545[ ln(hardness)] - 1.465)) |
q. | ≤ (0.791)(e(1.273[ ln(hardness)] - 1.460)) at hardness = 100. Conversion factor (CF) of 0.791 is hardness dependent. CF is calculated for other hardnesses as follows: CF = 1.46203 - [(ln hardness)(0.145712)]. |
r. | ≤ (0.791)(e(1.273[ ln(hardness)] - 4.705)) at hardness = 100. Conversion factor (CF) of 0.791 is hardness dependent. CF is calculated for other hardnesses as follows: CF = 1.46203 - [(ln hardness)(0.145712)]. |
s. | If the four-day average chronic concentration is exceeded more than once in a three-year period, the edible portion of the consumed species should be analyzed. Said edible tissue concentrations shall not be allowed to exceed 1.0 mg/kg of methylmercury. |
t. | ≤ (0.998)(e(0.8460[ ln(hardness)] + 3.3612)) |
u. | ≤ (0.997)(e(0.8460[ ln(hardness)] + 1.1645)) |
v. | ≤ e[1.005(pH) - 5.290] |
w. | ≤ e[1.005(pH) - 4.830] |
x. | The status of the fish community should be monitored whenever the concentration of selenium exceeds 5.0 ug/ l in salt water. |
y. | ≤ (0.85)(e(1.72[ln(hardness)] - 6.52)) |
z. | Channel Catfish may be more acutely sensitive. |
aa. | ≤ (0.978)(e(0.8473[ln(hardness)] + 0.8604)) |
bb. | ≤ (0.986)(e(0.8473[ln(hardness)] + 0.7614)) |
cc. | Nonlethal effects (growth, C-14 uptake, and chlorophyll production) to diatoms (Thalassiosira aestivalis and Skeletonema costatum) which are common to Washington's waters have been noted at levels below the established criteria. The importance of these effects to the diatom populations and the aquatic system is sufficiently in question to persuade the state to adopt the USEPA National Criteria value (36 µg/L) as the state threshold criteria, however, wherever practical the ambient concentrations should not be allowed to exceed a chronic marine concentration of 21 µg/L. |
dd. | These ambient criteria in the table are for the dissolved fraction. The cyanide criteria are based on the weak acid dissociable method. The metals criteria may not be used to calculate total recoverable effluent limits unless the seasonal partitioning of the dissolved to total metals in the ambient water are known. When this information is absent, these metals criteria shall be applied as total recoverable values, determined by back-calculation, using the conversion factors incorporated in the criterion equations. Metals criteria may be adjusted on a site-specific basis when data are made available to the department clearly demonstrating the effective use of the water effects ratio approach established by USEPA, as generally guided by the procedures in USEPA Water Quality Standards Handbook, December 1983, as supplemented or replaced by USEPA or ecology. The adjusted site specific criteria are not in effect until they have been incorporated into this chapter and approved by EPA. Information which is used to develop effluent limits based on applying metals partitioning studies or the water effects ratio approach shall be identified in the permit fact sheet developed pursuant to WAC 173-220-060 or 173-226-110, as appropriate, and shall be made available for the public comment period required pursuant to WAC 173-220-050 or 173-226-130(3), as appropriate. Ecology has developed supplemental guidance for conducting water effect ratio studies. |
ee. | The criteria for cyanide is based on the weak acid dissociable method in the 19th Ed. Standard Methods for the Examination of Water and Wastewater, 4500-CN I, and as revised (see footnote dd, above). |
ff. | These criteria are based on the total-recoverable fraction of the metal. |
gg. | Where methods to measure trivalent chromium are unavailable, these criteria are to be represented by total-recoverable chromium. |
hh. | The listed fresh water criteria are based on un-ionized or total ammonia concentrations, while those for marine water are based on un-ionized ammonia concentrations. Tables for the conversion of total ammonia to un-ionized ammonia for freshwater can be found in the USEPA's Quality Criteria for Water, 1986. Criteria concentrations based on total ammonia for marine water can be found in USEPA Ambient Water Quality Criteria for Ammonia (Saltwater)-1989, EPA440/5-88-004, April 1989. |
ii. | The conversion factor used to calculate the dissolved metal concentration was 0.982. |
jj. | The conversion factor used to calculate the dissolved metal concentration was 0.962. |
kk. | The conversion factor used to calculate the dissolved metal concentration was 0.85. |
ll. | Marine conversion factors (CF) which were used for calculating dissolved metals concentrations are given below. Conversion factors are applicable to both acute and chronic criteria for all metals except mercury. The CF for mercury was applied to the acute criterion only and is not applicable to the chronic criterion. Conversion factors are already incorporated into the criteria in the table. Dissolved criterion = criterion x CF |
Metal | CF | ||
Arsenic | 1.000 | ||
Cadmium | 0.994 | ||
Chromium (VI) | 0.993 | ||
Copper | 0.83 | ||
Lead | 0.951 | ||
Mercury | 0.85 | ||
Nickel | 0.990 | ||
Selenium | 0.998 | ||
Silver | 0.85 | ||
Zinc | 0.946 |
mm. | The cyanide criteria are: 2.8µg/l chronic and 9.1µg/l acute and are applicable only to waters which are east of a line from Point Roberts to Lawrence Point, to Green Point to Deception Pass; and south from Deception Pass and of a line from Partridge Point to Point Wilson. The chronic criterion applicable to the remainder of the marine waters is l µg/L.)) |
Compound/Chemical | Chemical Abstracts Service (CAS)# | Aquatic Life Criteria - Freshwater | Aquatic Life Criteria - Marine Water | Human Health Criteria for Consumption of: | |||
Acute | Chronic | Acute | Chronic | Water & Organisms | Organisms Only | ||
Metals: | |||||||
Aluminum | 7429905 | West: 510 East: 820 (a,e) | West: 270 East: 480 (b,e) | - | - | - | - |
Antimony | 7440360 | - | - | - | - | 12 (H) | 180 (H) |
Arsenic | 7440382 | 300 (a,f) | 130 (b,f) | 27 (a,f,g) | 12 (b,f,g) | 10 (A,H) | 10 (A,H) |
Asbestos | 1332214 | - | - | - | - | 7,000,000 fibers/L (C) | - |
Beryllium | 7440417 | - | - | - | - | - | - |
Cadmium | 7440439 | (a,f,h) | (b,f,i) | 33 (a,f) | 7.9 (b,f) | - | - |
Chromium (III) | 16065831 | (a,j,k) | (b,j,ll) | - | - | - | - |
Chromium (VI) | 18540299 | 18 (a,f,m) | 4.5 (b,f,n) | 1,100.0 (a,f,g) | 50.0 (b,f,g) | - | - |
Copper | 7440508 | West: 2.0 East: 2.5 (a,f,o) | West: 1.6 East: 1.8 (b,f,p) | 4.8 (a,f,g) | 3.1 (b,f,g) | 1,300 (C) | - |
Lead | 7439921 | (a,f,q) | (b,f,r) | 210.0 (a,f,g) | 8.1 (b,f,g) | - | - |
Mercury | 7439976 | 1.4 (a,f,s) | 0.012 (b,t,u) | 1.8 (a,f,g) | 0.025 (b,t,u) | (G) | (G) |
Methylmercury | 22967926 | - | - | - | - | - | - (H) |
Nickel | 7440020 | (a,f,v) | (b,f,w) | 74.0 (a,f,g) | 8.2 (b,f,g) | 150 (H) | 190 (H) |
Selenium | 7782492 | (x) | (y) | 290 (a,f,g) | 71.0 (b,f,g) | 120 (H) | 480 (H) |
Silver | 7440224 | (a,f,z) | (b,f,aa) | 2.2 (a,f,g) | 0.87 (b,f,g) | - | - |
Thallium | 7440280 | - | - | - | - | 0.24 | 0.27 |
Zinc | 7440666 | (a,f,bb) | (b,f,cc) | 90.0 (a,f,g) | 81.0 (b,f,g) | 2,300 (H) | 2,900 (H) |
Other chemicals: | |||||||
1,1,1-Trichloroethane | 71556 | - | - | - | - | 47,000 (H) | 160,000 (H) |
1,1,2,2-Tetrachloroethane | 79345 | - | - | - | - | 0.12 (B,H) | 0.46 (B,H) |
1,1,2-Trichloroethane | 79005 | - | - | - | - | 0.44 (B,H) | 1.8 (B,H) |
1,1-Dichloroethane | 75343 | - | - | - | - | - | - |
1,1-Dichloroethylene | 75354 | - | - | - | - | 1200 (H) | 4100 (H) |
1,2,4-Trichlorobenzene | 120821 | - | - | - | - | 0.12 (B,H) | 0.14 (B,H) |
1,2-Dichlorobenzene | 95501 | - | - | - | - | 2000 (H) | 2500 (H) |
1,2-Dichloroethane | 107062 | - | - | - | - | 9.3 (B,H) | 120 (B,H) |
1,2-Dichloropropane | 78875 | - | - | - | - | 0.71 (B) | 3.1 (B) |
1,3-Dichloropropene | 542756 | - | - | - | - | 0.24 (B) | 2 (B) |
1,2-Diphenylhydrazine | 122667 | - | - | - | - | 0.015 (B,H) | 0.023 (B,H) |
1,2-Trans-Dichloroethylene | 156605 | - | - | - | - | 600 (H) | 5,800 (H) |
1,3-Dichlorobenzene | 541731 | - | - | - | - | 13 (H) | 16 (H) |
1,4-Dichlorobenzene | 106467 | - | - | - | - | 460 (H) | 580 (H) |
2,3,7,8-TCDD (Dioxin) | 1746016 | - | - | - | - | 0.000000064 | 0.000000064 |
2,4,6-Trichlorophenol | 88062 | - | - | - | - | 0.25 (B) | 0.28 (B) |
2,4-Dichlorophenol | 120832 | - | - | - | - | 25 (H) | 34 (H) |
2,4-Dimethylphenol | 105679 | - | - | - | - | 85 | 97 |
2,4-Dinitrophenol | 51285 | - | - | - | - | 60 (H) | 610 (H) |
2,4-Dinitrotoluene | 121142 | - | - | - | - | 0.039 (B) | 0.18 (B) |
2,6-Dinitrotoluene | 606202 | - | - | - | - | - | - |
2-Chloroethyvinyl Ether | 110758 | - | - | - | - | - | - |
2-Chloronaphthalene | 91587 | - | - | - | - | 170 (H) | 180 (H) |
2-Chlorophenol | 95578 | - | - | - | - | 15 | 17 |
2-Methyl-4,6-Dinitrophenol (4,6-dinitro-o-cresol) | 534521 | - | - | - | - | 7.1 (H) | 25 (H) |
2-Nitrophenol | 88755 | - | - | - | - | - | - |
3,3'-Dichlorobenzidine | 91941 | - | - | - | - | 0.0031 (B) | 0.0033 (B) |
3-Methyl-4-Chlorophenol (parachlorometa cresol) | 59507 | - | - | - | - | 36 | 36 |
4,4'-DDD | 72548 | - | - | - | - | 0.000036 (B,H) | 0.000036 (B,H) |
4,4'-DDE | 72559 | - | - | - | - | 0.000051 (B,H) | 0.000051 (B,H) |
4,4'-DDT | 50293 | - | - | - | - | 0.000025 (B,H) | 0.000025 (B,H) |
4,4'-DDT (and metabolites) | 50293 | 1.1 (c) | 0.001 (d) | 0.13 (c) | 0.001 (d) | - | - |
4-Bromophenyl Phenyl Ether | 101553 | - | - | - | - | - | - |
4-Chorophenyl Phenyl Ether | 7005723 | - | - | - | - | - | - |
4-Nitrophenol | 100027 | - | - | - | - | - | - |
Acenaphthene | 83329 | - | - | - | - | 110 (H) | 110 (H) |
Acenaphthylene | 208968 | - | - | - | - | - | - |
Acrolein | 107028 | 3 (a) | 3 (b) | - | - | 1.0 | 1.1 |
Acrylonitrile | 107131 | - | - | - | - | 0.019 (B) | 0.028 (B) |
Aldrin | 309002 | 3 (c,dd) | 0.0019 (d,dd) | 1.3 (c,e) | 0.0019 (d,dd) | 0.0000057 (B,H) | 0.0000058 (B,H) |
alpha-BHC | 319846 | - | - | - | - | 0.0005 (B,H) | 0.00056 (B,H) |
alpha-Endosulfan | 959988 | 0.22 (c,ee) | 0.056 (d,ee) | 0.034 (c,ee) | 0.0087 (d,ee) | 9.7 (H) | 10 (H) |
Ammonia | 7664417 | (a,ff,ii) | (b,gg,ii) | 0.233 (a,hh,ii) | 0.035 (b,hh,ii) | - | - |
Anthracene | 120127 | - | - | - | - | 3,100 (H) | 4,600 (H) |
Benzene | 71432 | - | - | - | - | 0.44 (B) | 1.6 (B) |
Benzidine | 92875 | - | - | - | - | 0.00002 (B) | 0.000023 (B) |
Benzo(a) Anthracene | 56553 | - | - | - | - | 0.014 (B,H) | 0.021 (B,H) |
Benzo(a) Pyrene | 50328 | - | - | - | - | 0.0014 (B,H) | 0.0021 (B,H) |
Benzo(b) Fluoranthene | 205992 | - | - | - | - | 0.014 (B,H) | 0.021 (B,H) |
Benzo(ghi) Perylene | 191242 | - | - | - | - | - | - |
Benzo(k) Fluoranthene | 207089 | - | - | - | - | 0.014 (B,H) | 0.21 (B,H) |
beta-BHC | 319857 | - | - | - | - | 0.0018 (B,H) | 0.002 (B,H) |
beta-Endosulfan | 33213659 | 0.22 (c,ee) | 0.056 (d,ee) | 0.034 (c,ee) | 0.0087 (d,ee) | 9.7 | 10 |
Bis(2-Chloroethoxy) Methane | 111911 | - | - | - | - | - | - |
Bis(2-Chloroethyl) Ether | 111444 | - | - | - | - | 0.02 (B) | 0.06 (B) |
Bis(2-Chloroisopropyl) Ether | 39638329 | - | - | - | - | - (H) | - (H) |
Bis(2-Ethylhexyl) Phthalate | 117817 | - | - | - | - | 0.23 (B,H) | 0.25 (B,H) |
Bromoform | 75252 | - | - | - | - | 5.8 (B,H) | 27 (B,H) |
Butylbenzyl Phthalate | 85687 | - | - | - | - | 0.56 (B,H) | 0.58 (B,H) |
Carbaryl | 63252 | 2.1 (a) | 2.1 (b) | 1.6 (a) | - | - | - |
Carbon Tetrachloride | 56235 | - | - | - | - | 0.2 (B) | 0.35 (B) |
Chlordane | 57749 | 2.4 (c) | 0.0043 (d) | 0.09 (c) | 0.004 (d) | 0.000093 (B,H) | 0.000093 (B,H) |
Chloride (dissolved) | 168870 | 860 (a,hh,jj) | 230 (b,hh,jj) | - | - | - | - |
Chlorine (total residual) | 7782505 | 19 (a) | 11 (b) | 13 (a) | 7.5 (b) | - | - |
Chlorobenzene | 108907 | - | - | - | - | 380 (H) | 890 (H) |
Chlorodibromomethane | 124481 | - | - | - | - | 0.65 (B,H) | 3 (B,H) |
Chloroethane | 75003 | - | - | - | - | - | - |
Chloroform | 67663 | - | - | - | - | 260 (H) | 1200 (H) |
Chlorpyrifos | 2921882 | 0.083 (a) | 0.041 (b) | 0.011 (a) | 0.0056 (b) | - | - |
Chrysene | 218019 | - | - | - | - | 1.4 (B,H) | 2.1 (B,H) |
Cyanide | 57125 | 12 (a,kk) | 2.7 (b,kk) | 1.0 (a,kk,ll) | 1.0 (b,kk,ll) | 19 (D,H) | 270 (D,H) |
delta-BHC | 319868 | - | - | - | - | - | - |
Demeton | 8065483 | - | 0.1 (b) | - | 0.1 (b) | - | - |
Diazinon | 333415 | 0.17 (a) | 0.17 (b) | 0.82 (a) | 0.82 (b) | - | - |
Dibenzo(a,h) Anthracene | 53703 | - | - | - | - | 0.0014 (B,H) | 0.0021 (B,H) |
Dichlorobromomethane | 75274 | - | - | - | - | 0.77 (B,H) | 3.6 (B,H) |
Dieldrin | 60571 | 0.24 (a,dd) | 0.056 (b,dd) | 0.71 (c,dd) | 0.0019 (d,dd) | 0.0000061 (B,H) | 0.0000061 (B,H) |
Diethyl Phthalate | 84662 | - | - | - | - | 4,200 (H) | 5,000 (H) |
Dimethyl Phthalate | 131113 | - | - | - | - | 92,000 (H) | 130,000 (H) |
Di-n-Butyl Phthalate | 84742 | - | - | - | - | 450 (H) | 510 (H) |
Di-n-Octyl Phthalate | 117840 | - | - | - | - | - | - |
Endosulfan Sulfate | 1031078 | - | - | - | - | 9.7 (H) | 10 |
Endrin | 72208 | 0.086 (a) | 0.036 (b) | 0.037 (c) | 0.0023 (d) | 0.034 (H) | 0.035 (H) |
Endrin Aldehyde | 7421934 | - | - | - | - | 0.034 | 0.035 |
Ethylbenzene | 100414 | - | - | - | - | 200 (H) | 270 (H) |
Fluoranthene | 206440 | - | - | - | - | 16 (H) | 16 (H) |
Fluorene | 86737 | - | - | - | - | 420 (H) | 610 (H) |
Guthion | 86500 | - | 0.01 (b) | - | 0.01 (b) | - | - |
Hexachlorocyclohexane (gamma-BHC; Lindane) | 58899 | 0.95 (a) | 0.08 (d) | 0.16 (c) | - | 15 (H) | 17 (H) |
Heptachlor | 76448 | 0.52 (c) | 0.0038 (d) | 0.053 (c) | 0.0036 (d) | 0.0000099 (B,H) | 0.00001 (B,H) |
Heptachlor Epoxide | 1024573 | - | - | - | - | 0.0000074 (B,H) | 0.0000074 (B,H) |
Hexachlorobenzene | 118741 | - | - | - | - | 0.000051 (B,H) | 0.000052 (B,H) |
Hexachlorobutadiene | 87683 | - | - | - | - | 0.69 (B,H) | 4.1 (B,H) |
Hexachlorocyclopentadiene | 77474 | - | - | - | - | 150 (H) | 630 (H) |
Hexachloroethane | 67721 | - | - | - | - | 0.11 (B,H) | 0.13 (B,H) |
Indeno(1,2,3-cd) Pyrene | 193395 | - | - | - | - | 0.014 (B,H) | 0.021 (B,H) |
Isophorone | 78591 | - | - | - | - | 27 (B) | 110 (B) |
Malathion | 121755 | - | 0.1 (b) | - | 0.1 (b) | - | - |
Methoxychlor | 72435 | - | 0.3 (b) | - | 0.3 (b) | - | - |
Methyl Bromide | 74839 | - | - | - | - | 520 (H) | 2,400 |
Methyl Chloride | 74873 | - | - | - | - | - | - |
Methylene Chloride | 75092 | - | - | - | - | 16 (B,H) | 250 (B,H) |
Mirex | 2385855 | - | 0.001 (b) | - | 0.001 (b) | - | - |
N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine-quinone(6PPD-q) | 0.008 (c) | - | - | - | - | - | |
Napthalene | 91203 | - | - | - | - | - | - |
Nitrobenzene | 98953 | - | - | - | - | 55 (H) | 320 (H) |
N-Nitrosodimethylamine | 62759 | - | - | - | - | 0.00065 (B) | 0.34 (B) |
N-Nitrosodi-n-Propylamine | 621647 | - | - | - | - | 0.0044 (B) | 0.058 (B) |
N-Nitrosodiphenylamine | 86306 | - | - | - | - | 0.62 (B) | 0.69 (B) |
Nonylphenol | 84852153 | 28 (a) | 6.6 (b) | 7 (a) | 1.7 (b) | - | - |
Parathion | 56382 | 0.065 (a) | 0.013 (b) | - | - | - | - |
Pentachlorophenol (PCP) | 87865 | (a,mm) | (b,nn) | 13 (a) | 6.7 (b) | 0.046 (B,H) | 0.1 (B,H) |
Perfluorooctane sulfonic acid (PFOS) | 3000 (a) | (oo) | 550 (a) | - | - | - | |
Perfluorooctanoic acid (PFOA) | 49000 (a) | (pp) | 7000 (a) | - | - | - | |
Phenanthrene | 85018 | - | - | - | - | - | - |
Phenol | 108952 | - | - | - | - | 18,000 (H) | 200,000 (H) |
Polychlorinated Biphenyls (PCBs) | 2.0 (d) | 0.014 (d) | 10.0 (d) | 0.03 (d) | 0.00017 (E,H) | 0.00017 (E,H) | |
Pyrene | 129000 | - | - | - | - | 310 (H) | 460 (H) |
Tetrachloroethylene | 127184 | - | - | - | - | 4.9 (B,H) | 7.1 (B,H) |
Toluene | 108883 | - | - | - | - | 180 (H) | 410 (H) |
Toxaphene | 8001352 | 0.73 (a) | 0.0002 (b) | 0.21 (a) | 0.0002 (b) | 0.000032 (B) | 0.000032 (B) |
Tributyltin | 0.46 (a) | 0.072 (b) | 0.42 (a) | 0.0074 (b) | - | - | |
Trichloroethylene | 79016 | - | - | - | - | 0.38 (B,H) | 0.86 (B,H) |
Vinyl Chloride | 75014 | - | - | - | - | 0.02 (B,F) | 0.26 (B,F,H) |
Footnotes for aquatic life criteria in Table 240: | |
a. | A 1-hour average concentration not to be exceeded more than once every three years on the average. |
b. | A 4-day average concentration not to be exceeded more than once every three years on average. |
c. | An instantaneous concentration not to be exceeded at any time. |
d. | A 24-hour average not to be exceeded at any time. |
e. | Criteria are calculated using the Aluminum Criteria Calculator V.2.0 that is published in EPA's "Final Aquatic Water Quality Criteria for Aluminum 2018" (EPA-822-R-1-001). The freshwater default acute criterion of 510 µg/L is applicable in western Washington and 820 µg/L is the applicable default acute criterion in eastern Washington. The freshwater default chronic criterion of 270 µg/L is the applicable default criterion in western Washington and 480 µg/L is the applicable default chronic criterion in eastern Washington. The boundaries for eastern and western Washington are defined in WAC 222-16-010. The default criterion is used in the absence of concurrently sampled pH, hardness, and dissolved organic carbon for a site-specific location or water body. Criteria calculated using concurrently sampled pH, hardness, and dissolved organic carbon for a specific water body supersede the default criteria. |
f. | These ambient criteria in the table are for the dissolved fraction. The cyanide criteria are based on the weak acid dissociable method. The metals criteria may not be used to calculate total recoverable effluent limits unless the seasonal partitioning of the dissolved to total metals in the ambient water are known. When this information is absent, these metals criteria shall be applied as total recoverable values, determined by back-calculation, using the conversion factors incorporated in the criterion equations. Metals criteria may be adjusted on a site-specific basis when data are made available to the department clearly demonstrating the effective use of the water effects ratio approach established by USEPA, as generally guided by the procedures in USEPA Water Quality Standards Handbook, December 1983, as supplemented or replaced by USEPA or ecology. The adjusted site specific criteria are not in effect until they have been incorporated into this chapter and approved by EPA. Information which is used to develop effluent limits based on applying metals partitioning studies or the water effects ratio approach shall be identified in the permit fact sheet developed pursuant to WAC 173-220-060 or 173-226-110, as appropriate, and shall be made available for the public comment period required pursuant to WAC 173-220-050 or 173-226-130(3), as appropriate. Ecology has developed supplemental guidance for conducting water effect ratio studies. |
g. | Marine conversion factors (CF) which were used for calculating dissolved metals concentrations are given below. Conversion factors are applicable to both acute and chronic criteria for all metals except mercury. The CF for mercury was applied to the acute criterion only and is not applicable to the chronic criterion. Conversion factors are already incorporated into the criteria in the table. Dissolved criterion = criterion x CF |
Metal | CF | |
Arsenic | 1.000 | |
Cadmium | 0.994 | |
Chromium (VI) | 0.993 | |
Copper | 0.83 | |
Lead | 0.951 | |
Mercury | 0.85 | |
Nickel | 0.990 | |
Selenium | 0.998 | |
Silver | 0.85 | |
Zinc | 0.946 |
h. | Acute criterion = (CF)(e(0.9789[ln(hardness)]-4.189)). Conversion factor (CF) is hardness dependent. CF is calculated for other hardnesses as follows: CF = 1.136672 - [(ln hardness)(0.041838)]. |
i. | Chronic criterion = (CF)(e(0.7977[ln(hardness)]-4.446)). Conversion factor (CF) is hardness dependent. CF is calculated for other hardnesses as follows: CF = 1.101672 - [(ln hardness)(0.041838)]. |
j. | Where methods to measure trivalent chromium are unavailable, these criteria are to be represented by total-recoverable chromium. |
k. | Acute criterion = (0.316)(e(0.8190[ln(hardness)] + 3.7256)) |
l. | Chronic criterion = (0.860)(e(0.8190[ln(hardness)] + 0.6848)) |
m. | The conversion factor used to calculate the dissolved metal concentration is 0.982. |
n. | The conversion factor used to calculate the dissolved metal concentration is 0.962. |
o. | The acute criterion is represented by the higher criteria value of the two equations: 1) Acute criterion = e(0.700*ln(DOC) + 0.579*ln(hardness) + 0.778*pH – 6.738) and 2) Acute criterion = e(0.855*ln(DOC) + 0.221*ln(hardness) + 0.216*pH – 1.183). The freshwater default acute criterion of 2.0 µg/L is applicable in western Washington and 2.5 µg/L is the applicable default acute criterion in eastern Washington. The boundaries for eastern and western Washington are defined in WAC 222-16-010. The default criterion is used in the absence of concurrently sampled pH, hardness, and dissolved organic carbon for a site-specific location or water body. Criteria calculated using concurrently sampled pH, hardness, and dissolved organic carbon for a specific water body supersede the default criteria. |
p. | Chronic criterion = e(0.855*ln(DOC) + 0.221*ln(hardness) + 0.216*pH – 1.402) . The freshwater default chronic criterion of 1.6 µg/L is applicable in western Washington and 1.8 µg/L is the applicable default chronic criterion in eastern Washington. The boundaries for eastern and western Washington are defined in WAC 222-16-010. The default criterion is used in the absence of concurrently sampled pH, hardness, and dissolved organic carbon for a site-specific location or water body. Criteria calculated using concurrently sampled pH, hardness, and dissolved organic carbon for a specific water body supersede the default criteria. |
q. | Acute criterion = (CF)(e(1.273[ln(hardness)] - 1.460)). Conversion factor (CF) is hardness dependent. CF is calculated for other hardnesses as follows: CF = 1.46203 - [(ln hardness)(0.145712)]. |
r. | Chronic criterion = (CF)(e(1.273[ln(hardness)] - 4.705)). Conversion factor (CF) is hardness dependent. CF is calculated for other hardnesses as follows: CF = 1.46203 - [(ln hardness)(0.145712)]. |
s. | The conversion factor used to calculate the dissolved metal concentration is 0.85. |
t. | These criteria are based on the total-recoverable fraction of the metal. |
u. | If the four-day average chronic concentration is exceeded more than once in a three-year period, the edible portion of the consumed species should be analyzed. Said edible tissue concentrations shall not be allowed to exceed 1.0 mg/kg of methylmercury. |
v. | Acute criterion = (0.998)(e(0.8460[ln(hardness)] - 0.3604)) |
w. | Chronic criterion = (0.997)(e(0.8460[ln(hardness)] - 2.176)) |
x. | There is no freshwater acute criterion for aquatic life for selenium. The freshwater chronic criterion is expected to adequately protect against acute effects. |
y. | Freshwater chronic selenium criteria: |
15.1 mg/kg dry weight (egg-ovary tissue)1 | |
8.5 mg/kg dry weight (whole-body tissue)2 | |
11.3 mg/kg dry weight (muscle tissue)2 | |
1.5 ug/L (water lentic)3 | |
3.1 ug/L (water lotic)3 | |
WQCint = WQC – Cbkgrnd (1 – fint) / fint (water lentic or lotic)3,4 | |
1 Egg-ovary supersedes any whole-body, muscle, or water column element when fish egg-ovary concentrations are measured, except as noted in footnote 4. Tissue criterion is not to be exceeded. | |
2 Fish whole-body or muscle tissue supersedes the water column element when both fish tissue and water concentrations are measured, except as noted in footnote 4. Tissue criterion is not to be exceeded. | |
3 Water column values are based on dissolved total selenium in water and are derived from fish tissue values via bioaccumulation modeling. When selenium inputs are increasing, water column values are the applicable criterion element in the absence of steady-state condition fish tissue data. Water column criteria are based on a 30-day average concentrations, except for WQCint (see footnote 4). Water column criteria are not to be exceeded more than once every three years on average. | |
4 Where WQCint is the intermittent exposure concentration in ug/L; WQC is the applicable water column element, for either lentic or lotic waters; Cbkgrnd is the average daily background concentration occurring during the remaining time, integrated over 30 days; fint is the fraction of any 30-day period during which elevated selenium concentrations occur, with fint assigned a value ≥ 0.033 (corresponding to one day). Intermittent exposure criteria averaging period is the number of days per month with an elevated concentration. | |
z. | Acute criterion = (0.85)(e(1.72[ln(hardness)] – 8.420)) |
aa. | Chronic criterion = (0.85)(e(1.72[ln(hardness)] – 9.342)) |
bb. | Acute criterion = (0.978)(e(0.8473[ln(hardness)] + 0.1564)) |
cc. | Chronic criterion = (0.986)(e(0.8473[ln(hardness)] – 0.2323)) |
dd. | Aldrin is metabolically converted to Dieldrin. Therefore, the sum of the Aldrin and Dieldrin concentrations are compared with the Dieldrin criteria. |
ee. | This value was derived from data for endosulfan. Where concentrations for both alpha-endosulfan and beta-endosulfan are available, the sum of alpha-endosulfan and beta-endosulfan concentrations shall be compared to the criteria. |
ff. | Shall not exceed the numerical value in total ammonia nitrogen (mg N/L) given by: |
For salmonids present: | 0.275 | + | 39.0 |
1 + 107.204-pH | 1 + 10pH-7.204 | ||
For salmonids absent: | 0.411 | + | 58.4 |
1 + 107.204-pH | 1 + 10pH-7.204 |
gg. | Shall not exceed the numerical concentration calculated as follows: |
Unionized ammonia concentration for waters where salmonid habitat is an existing or designated use: |
0.80 ÷ (FT)(FPH)(RATIO) | ||||
where: | RATIO | = | 13.5; 7.7 ≤ pH ≤ 9 | |
RATIO | = | (20.25 x 10(7.7-pH)) ÷ (1 + 10(7.4-pH)); 6.5 ≤ pH ≤ 7.7 | ||
FT | = | 1.4; 15 ≤ T ≤ 30 | ||
FT | = | 10[0.03(20-T)]; 0 ≤ T ≤ 15 | ||
FPH | = | 1; 8 ≤ pH ≤ 9 | ||
FPH | = | (1 + 10(7.4-pH)) ÷ 1.25; 6.5 ≤ pH ≤ 8.0 |
where: A | = | the greater of either T (temperature in degrees Celsius) or 7. |
where: B | = | the lower of either 2.85, or 1.45 x 100.028 x (25-T). T = temperature in degrees Celsius. |
Applied as a 30-day average concentration of total ammonia nitrogen (in mg N/L) not to be exceeded more than once every three years on the average. The highest four-day average within the 30-day period should not exceed 2.5 times the chronic criterion. | |
hh. | Measured in milligrams per liter rather than micrograms per liter. |
ii. | The listed freshwater criteria are based on un-ionized or total ammonia concentrations, while those for marine water are based on un-ionized ammonia concentrations. Tables for the conversion of total ammonia to un-ionized ammonia for freshwater can be found in the USEPA's Quality Criteria for Water, 1986. Criteria concentrations based on total ammonia for marine water can be found in USEPA Ambient Water Quality Criteria for Ammonia (Saltwater)-1989, EPA440/5-88-004, April 1989. |
jj. | Criterion based on dissolved chloride in association with sodium. This criterion probably will not be adequately protective when the chloride is associated with potassium, calcium, or magnesium, rather than sodium. |
kk. | The criteria for cyanide is based on the weak acid dissociable method in the 19th Ed. Standard Methods for the Examination of Water and Wastewater, 4500-CN I, and as revised (see footnote f, above). |
ll. | The cyanide criteria are: 2.8 µg/L chronic and 9.1 µg/L acute and are applicable only to waters which are east of a line from Point Roberts to Lawrence Point, to Green Point to Deception Pass; and south from Deception Pass and of a line from Partridge Point to Point Wilson. The chronic criterion applicable to the remainder of the marine waters is l µg/L. |
mm. | Acute criterion = e[1.005(pH) – 5.595] |
nn. | Chronic criterion = e[1.005(pH) – 6.299] |
oo. | Freshwater chronic PFOS criteria: |
8.4 µg/L (water)1,2 | |
0.937 mg/kg ww (invertebrate whole-body)1,3,4 | |
6.75 mg/kg ww (fish whole-body)1,3,4 | |
2.91 mg/kg ww (fish muscle)1,3,4 | |
1 All water column and tissue criteria are intended to be independently applicable for compliance determinations and no one criterion takes primacy. | |
2 Water column criteria are based on a four-day average concentration not to be exceeded more than once every three years on average. | |
3 Tissue criteria derived from the chronic water column concentration with the use of bioaccumulation factors and are expressed as wet weight (ww) concentrations. | |
4 Tissue data is an instantaneous point measurement that reflect integrative accumulation of PFOS over time and space. Criteria are not to be exceeded more than once every 10 years on average. | |
pp. | Freshwater chronic PFOA criteria: |
94 µg/L (water)1,2 | |
1.11 mg/kg ww (invertebrate whole-body)1,3,4 | |
6.10 mg/kg ww (fish whole-body)1,3,4 | |
0.125 mg/kg ww (fish muscle)1,3,4 | |
1 All water column and tissue criteria are intended to be independently applicable for compliance determinations and no one criterion takes primacy. | |
2 Water column criteria are based on a four-day average concentration not to be exceeded more than once every three years on average. | |
3 Tissue criteria derived from the chronic water column concentration with the use of bioaccumulation factors and are expressed as wet weight (ww) concentrations. | |
4 Tissue data is an instantaneous point measurement that reflect integrative accumulation of PFOS over time and space. Criteria are not to be exceeded more than once every 10 years on average. |
Footnotes for human health criteria in Table 240: | |
A. | This criterion for total arsenic is the maximum contaminant level (MCL) developed under the Safe Drinking Water Act. The MCL for total arsenic is applied to surface waters where consumption of organisms-only and where consumption of water + organisms reflect the designated uses. When the department determines that a direct or indirect industrial discharge to surface waters designated for domestic water supply may be adding arsenic to its wastewater, the department will require the discharger to develop and implement a pollution prevention plan to reduce arsenic through the use of AKART. Industrial wastewater discharges to a privately or publicly owned wastewater treatment facility are considered indirect discharges. |
B. | This criterion was calculated based on an additional lifetime cancer risk of one-in-one-million (1 x 10-6 risk level). |
C. | This criterion is based on a regulatory level developed under the Safe Drinking Water Act. |
D. | This recommended water quality criterion is expressed as total cyanide, even though the integrated risk information system RfD used to derive the criterion is based on free cyanide. The multiple forms of cyanide that are present in ambient water have significant differences in toxicity due to their differing abilities to liberate the CN-moiety. Some complex cyanides require even more extreme conditions than refluxing with sulfuric acid to liberate the CN-moiety. Thus, these complex cyanides are expected to have little or no "bioavailability" to humans. If a substantial fraction of the cyanide present in a water body is present in a complexed form (e.g., Fe4[Fe(CN)6]3), this criterion may be overly conservative. |
E. | This criterion applies to total PCBs, (e.g., the sum of all congener or all isomer or homolog or Aroclor analyses). The PCBs criteria were calculated using a chemical-specific risk level of 4 x 10-5. Because that calculation resulted in a higher (less protective) concentration than the current criterion concentration (40 C.F.R. 131.36) the state made a chemical-specific decision to stay at the current criterion concentration. |
F. | This criterion was derived using the cancer slope factor of 1.4 (linearized multistage model with a twofold increase to 1.4 per mg/kg-day to account for continuous lifetime exposure from birth). |
G. | ((The human health criteria for mercury are contained in 40 C.F.R. 131.36.))EPA has removed Washington from the National Toxics Rule at 40 C.F.R. 131.36 for mercury and promulgated new human health criteria for methylmercury in the EPA's final federal rule at 40 C.F.R. 131.45. |
H. | Human health criteria applicable for Clean Water Act purposes in the state of Washington are contained in 40 C.F.R. 131.45 and effective as of December 19, 2022 (87 FR 69183). |