[Equation 745-1] |
Soil Cleanup Level (mg/kg) | = | RfD x ABW x UCF x HQ x AT |
SIR x AB1 x EF x ED |
Where: |
RfD | = | Reference dose as specified in WAC 173-340-708(7) (mg/kg-day) |
ABW | = | Average body weight over the exposure duration (70 kg) |
UCF | = | Unit conversion factor (1,000,000 mg/kg) |
SIR | = | Soil ingestion rate (50 mg/day) |
AB1 | = | Gastrointestinal absorption fraction (1.0) (unitless) |
EF | = | Exposure frequency (0.4) (unitless) |
HQ | = | Hazard quotient (1) (unitless) |
AT | = | Averaging time (20 years) |
ED | = | Exposure duration (20 years) |
(II) Carcinogens. For carcinogenic effects of hazardous substances due to soil ingestion, concentrations shall be determined using Equation 745-2. For petroleum mixtures and components of such mixtures, see (b)(iii)(B)(III) of this subsection.
[Equation 745-2] |
Soil Cleanup Level (mg/kg) | = | RISK x ABW x AT x UCF |
CPF x SIR x AB1 x ED x EF |
Where: |
RISK | = | Acceptable cancer risk level (1 in 100,000) (unitless) |
ABW | = | Average body weight over the exposure duration (70 kg) |
AT | = | Averaging time (75 years) |
UCF | = | Unit conversion factor (1,000,000 mg/kg) |
CPF | = | Carcinogenic Potency Factor as specified in WAC 173-340-708(8) (kg-day/mg) |
SIR | = | Soil ingestion rate (50 mg/day) |
AB1 | = | Gastrointestinal absorption fraction (1.0) (unitless). May use 0.6 for mixtures of dioxins and/or furans |
ED | = | Exposure duration (20 years) |
EF | = | Exposure frequency (0.4) (unitless) |
(III) Petroleum mixtures. For noncarcinogenic effects of petroleum mixtures, a total petroleum hydrocarbon cleanup level shall be calculated taking into account the additive effects of the petroleum fractions and volatile organic compounds present in the petroleum mixture. Equation 745-3 shall be used for this calculation. This equation takes into account concurrent exposure due to ingestion and dermal contact with petroleum contaminated soils. Cleanup levels for other noncarcinogens and known or suspected carcinogens within the petroleum mixture shall be calculated using Equations 745-4 and 745-5. See Table 830-1 for the analyses required for various petroleum products to use this method.
[Equation 745-3]
Where: |
Csoil | = | TPH soil cleanup level (mg/kg) |
HI | = | Hazard index (1) (unitless) |
ABW | = | Average body weight over the exposure duration (70 kg) |
AT | = | Averaging time (20 years) |
EF | = | Exposure frequency (0.7) (unitless) |
ED | = | Exposure duration (20 years) |
SIR | = | Soil ingestion rate (50 mg/day) |
AB1 | = | Gastrointestinal absorption fraction (1.0) (unitless) |
F(i) | = | Fraction (by weight) of petroleum component (i) (unitless) |
SA | = | Dermal surface area (2,500 cm2) |
AF | = | Adherence factor (0.2 mg/cm2-day) |
ABS | = | Dermal absorption fraction for petroleum component (i) (unitless). May use chemical-specific values or the following defaults: |
| • | 0.0005 for volatile petroleum components with vapor press ˃ = benzene |
| • | 0.03 for volatile petroleum components with vapor press < benzene |
| • | 0.1 for other petroleum components |
RfDo(i) | = | Oral reference dose of petroleum component (i) as defined in WAC 173-340-708(7) (mg/kg-day) |
RfDd(i) | = | Dermal reference dose for petroleum component (i) (mg/kg-day) derived by RfDo x GI |
GI | = | Gastrointestinal absorption conversion factor (unitless). May use chemical-specific values or the following defaults: |
| • | 0.8 for volatile petroleum components |
| • | 0.5 for other petroleum components |
n | = | The number of petroleum components (petroleum fractions plus volatile organic compounds with an RfD) present in the petroleum mixture. (See Table 830-1.) |
(C) Soil vapors. The soil to vapor pathway shall be evaluated for volatile organic compounds whenever any of the following conditions exist:
(I) For gasoline range organics, whenever the total petroleum hydrocarbon (TPH) concentration is significantly higher than a concentration derived for protection of groundwater for drinking water beneficial use under WAC
173-340-747(6) using the default assumptions;
(II) For diesel range organics, whenever the total petroleum hydrocarbon (TPH) concentration is greater than 10,000 mg/kg;
(III) For other volatile organic compounds, including petroleum components, whenever the concentration is significantly higher than a concentration derived for protection of groundwater for drinking water beneficial use under WAC
173-340-747(4).
See subsection (5)(c)(iv)(B) of this section for methods that may be used to evaluate the soil to vapor pathway.
(c) Modified Method C soil cleanup levels.
(i)
General. Modified Method C soil cleanup levels are standard Method C soil cleanup levels modified with chemical-specific or site-specific data. When making these adjustments, the resultant cleanup levels shall meet applicable state and federal laws, meet health risk levels for standard Method C soil cleanup levels, and be demonstrated to be environmentally protective using the procedures specified in WAC
173-340-7490 through
173-340-7494. Changes to exposure assumptions must comply with WAC
173-340-708(10).
(ii) Allowable modifications. The following modifications may be made to the default assumptions in the standard Method C equations to derive modified Method C soil cleanup levels:
(A) For the protection of groundwater see WAC
173-340-747;
(B) For soil ingestion, the gastrointestinal absorption fraction may be modified if the requirements of WAC
173-340-702 (14), (15), (16), and
173-340-708(10) are met;
(C) For dermal contact, the adherence factor, dermal absorption fraction and gastrointestinal absorption conversion factor may be modified if the requirements of WAC
173-340-702 (14), (15), (16), and
173-340-708(10) are met;
(D) The toxicity equivalent factors provided in WAC
173-340-708 (8)(d), (e) and (f), may be modified provided the requirements of WAC
173-340-708 (8)(g) and (h) are met;
(E) The reference dose and cancer potency factor may be modified if the requirements in WAC
173-340-708 (7) and (8) are met; and
(F) Modifications incorporating new science as provided for in WAC
173-340-702 (14), (15) and (16).
(iii) Dermal contact. For hazardous substances other than petroleum mixtures, dermal contact with the soil shall be evaluated whenever the proposed changes to Equations 745-1 and 745-2 would result in a significantly higher soil cleanup level than would be calculated without the proposed changes. When conducting this evaluation, the following equations and default assumptions shall be used:
(A) For noncarcinogens use Equation 745-4. This equation takes into account concurrent exposure due to ingestion and dermal contact with soil.
[Equation 745-4]
Where: |
Csoil | = | Soil cleanup level (mg/kg) |
HQ | = | Hazard quotient (unitless) |
ABW | = | Average body weight over the exposure duration (70 kg) |
AT | = | Averaging time (20 years) |
EF | = | Exposure frequency (0.7) (unitless) |
ED | = | Exposure duration (20 years) |
SIR | = | Soil ingestion rate (50 mg/day) |
AB1 | = | Gastrointestinal absorption fraction (1.0) (unitless) |
SA | = | Dermal surface area (2,500 mg/cm2) |
AF | = | Adherence factor (0.2 mg/cm2-day) |
ABS | = | Dermal absorption fraction (unitless). May use chemical-specific values or the following defaults: |
| • | 0.01 for inorganic hazardous substances |
| • | 0.0005 for volatile organic compounds with vapor press ˃ = benzene |
| • | 0.03 for volatile organic compounds with vapor press < benzene |
| • | 0.1 for other organic hazardous substances |
RfDo | = | Oral reference dose as defined in WAC 173-340-708(7) (mg/kg-day) |
RfDd | = | Dermal reference dose (mg/kg-day) derived by RfDo x GI |
GI | = | Gastrointestinal absorption conversion factor (unitless). May use chemical-specific values or the following defaults: |
| • | 0.2 for inorganic hazardous substances |
| • | 0.8 for volatile organic compounds |
| • | 0.5 for other organic hazardous substances |
(B) For carcinogens use Equation 745-5. This equation takes into account concurrent exposure due to ingestion and dermal contact with soil.
[Equation 745-5]
Where: |
Csoil | = | Soil cleanup level (mg/kg) |
RISK | = | Acceptable cancer risk (1 in 100,000) (unitless) |
ABW | = | Average body weight over the exposure duration (70 kg) |
AT | = | Averaging time (75 years) |
EF | = | Exposure frequency (0.7) (unitless) |
ED | = | Exposure duration (20 years) |
SIR | = | Soil ingestion rate (50 mg/day) |
AB1 | = | Gastrointestinal absorption fraction (1.0) (unitless). May use 0.6 for mixtures of dioxins and/or furans |
CPFo | = | Oral cancer potency factor as defined in WAC 173-340-708(8) (kg-day/mg) |
CPFd | = | Dermal cancer potency factor (kg-day/mg) derived by CPFo/GI |
GI | = | Gastrointestinal absorption conversion factor (unitless). May use chemical-specific values or the following defaults: |
| • | 0.2 for inorganic hazardous substances |
| • | 0.8 for volatile organic compounds and mixtures of dioxins and/or furans |
| • | 0.5 for other organic hazardous substances |
SA | = | Dermal surface area (2,500 cm2) |
AF | = | Adherence factor (0.2 mg/cm2-day) |
ABS | = | Dermal absorption fraction (unitless). May use chemical-specific values or the following defaults: |
| • | 0.01 for inorganic hazardous substances |
| • | 0.0005 for volatile organic compounds with vapor press ˃ = benzene |
| • | 0.03 for volatile organic compounds substances with vapor press < benzene and for mixtures of dioxins and/or furans |
| • | 0.1 for other organic hazardous substances |
(C) Modifications may be made to Equations 745-4 and 745-5 as provided for in subsection (5)(c)(ii) of this section.
(iv) Soil vapors.
(A) Applicability. The soil to vapor pathway shall be evaluated for volatile organic compounds whenever any of the following conditions exist:
(I) For other than petroleum hydrocarbon mixtures, the proposed changes to the standard Method C equations (Equations 745-1 and 745-2) or default values would result in a significantly higher soil cleanup level than would be calculated without the proposed changes;
(II) For petroleum hydrocarbon mixtures, the proposed changes to the standard Method C equations (Equations 745-3, 745-4 and 745-5) or default values would result in a significantly higher soil cleanup level than would be calculated without the proposed changes;
(III) For gasoline range organics, whenever the total petroleum hydrocarbon (TPH) concentration is significantly higher than a concentration derived for protection of groundwater for drinking water beneficial use under WAC
173-340-747(6) using the default assumptions;
(IV) For diesel range organics, whenever the total petroleum hydrocarbon (TPH) concentration is greater than 10,000 mg/kg;
(V) For other volatile organic compounds, including petroleum components, whenever the concentration is significantly higher than a concentration derived for protection of groundwater for drinking water beneficial use under WAC
173-340-747(4).
(B) Evaluation methods. Soil cleanup levels that are protective of the indoor and ambient air shall be determined on a site-specific basis. Soil cleanup levels may be evaluated as being protective of air pathways using any of the following methods:
(I) Measurements of the soil vapor concentrations, using methods approved by the department, demonstrating vapors in the soil would not exceed air cleanup levels established under WAC
173-340-750.
(II) Measurements of ambient air concentrations and/or indoor air vapor concentrations throughout buildings, using methods approved by the department, demonstrating air does not exceed cleanup levels established under WAC
173-340-750. Such measurements must be representative of current and future site conditions when vapors are likely to enter and accumulate in structures. Measurement of ambient air may be excluded if it can be shown that indoor air is the most protective point of exposure.
(III) Use of modeling methods approved by the department to demonstrate the air cleanup standards established under WAC
173-340-750 will not be exceeded. When this method is used, the department may require soil vapor and/or air monitoring to be conducted to verify the calculations and compliance with air cleanup standards.
(IV) Other methods as approved by the department demonstrating the air cleanup standards established under WAC
173-340-750 will not be exceeded.
(d)
Using modified Method C to evaluate industrial soil remediation levels. In addition to the adjustments allowed under subsection (5)(c) of this section,other adjustmentsto the reasonable maximum exposure scenario or default exposure assumptions are allowed when using a quantitative site-specific risk assessment to evaluate the protectiveness of a remedy. See WAC
173-340-355,
173-340-357, and
173-340-708 (3)(d) and (10)(b).
(6) Adjustments to industrial soil cleanup levels.
(a)
Total site risk adjustments. Soil cleanup levels for individual hazardous substances developed in accordance with subsection (5) of this section, including cleanup levels based on state and federal laws, shall be adjusted downward to take into account exposure to multiple hazardous substances and/or exposure resulting from more than one pathway of exposure. These adjustments need to be made only if, without these adjustments, the hazard index would exceed one (1) or the total excess cancer risk would exceed one in one hundred thousand (1 x 10
-5). These adjustments shall be made in accordance with the procedures specified in WAC
173-340-708 (5) and (6). In making these adjustments, the hazard index shall not exceed one (1) and the total excess cancer risk shall not exceed one in one hundred thousand (1 x 10
-5).
(b) Adjustments to applicable state and federal laws. Where a cleanup level developed under subsection (3) or (5) of this section is based on an applicable state or federal law and the level of risk upon which the standard is based exceeds an excess cancer risk of one in one hundred thousand (1 x 10-5) or a hazard index of one (1), the cleanup level shall be adjusted downward so that total excess cancer risk does not exceed one in one hundred thousand (1 x 10-5) and the hazard index does not exceed one (1) at the site.
(c)
Natural background and analytical considerations. Cleanup levels determined under subsection (3) or (5) of this section, including cleanup levels adjusted under subsection (6)(a) and (b) of this section, shall not be set at levels below the practical quantitation limit or natural background concentration, whichever is higher. See WAC
173-340-707 and
173-340-709 for additional requirements pertaining to practical quantitation limits and natural background.
(7)
Point of compliance. The point of compliance for industrial property soil cleanup levels shall be established in accordance with WAC
173-340-740(6).
(8)
Compliance monitoring. Compliance monitoring and data analysis and evaluation for industrial property soil cleanup levels shall be performed in accordance with WAC
173-340-410 and
173-340-740(7).
[Statutory Authority: RCW
70.105D.030(2). WSR 07-21-065 (Order 06-10), § 173-340-745, filed 10/12/07, effective 11/12/07. Statutory Authority: Chapter
70.105D RCW. WSR 01-05-024 (Order 97-09A), § 173-340-745, filed 2/12/01, effective 8/15/01; WSR 96-04-010 (Order 94-37), § 173-340-745, filed 1/26/96, effective 2/26/96; WSR 91-04-019, § 173-340-745, filed 1/28/91, effective 2/28/91.]
Reviser's note: The brackets and enclosed material in the text of the above section occurred in the copy filed by the agency.