WSR 98-10-029
PERMANENT RULES
DEPARTMENT OF
LABOR AND INDUSTRIES
[Filed April 24, 1998, 11:30 a.m., effective July 24, 1998]
Date of Adoption: April 24, 1998.
Purpose: Air contaminants, chapter 296-62 WAC, General occupational health standards, the department began review of WAC 296-62-07515 Control of Chemical Agents Table 1: Limits for Air Contaminant Permissible Exposure Limits (PEL) after OSHA published correcting amendments August 4, 1997, in the Federal Register (Volume 61, Number 149, page 42018). Based on that review, permanent amendments are made to WAC 296-62-07515 Control of chemical agents and WAC 296-62-07477 Appendix C for the methylene chloride standard as described below.
Amended WAC 296-62-07515 Control of chemical agents, a federal-initiated amendment adds the abbreviation "(DBCP)" to Dibromo-d-chloropropane. No new compliance requirements are added. No other federal-initiated amendments are made.
State-initiated amendments are being made to Table 1: Limits for Air Contaminants Permissible Exposure Limits (PEL). The following amendments establish new compliance requirements.
Chromic acid and chromates (as CrO3) PEL is changed from 0.1 mg/m3 TWA (time-weighted average) to 0.1 mg/m3 ceiling limit making this PEL identical to OSHA's rule (Code of Federal Regulations 1910.1000 Table Z-1 and Z-2) and WISHA at least as effective as OSHA. This reverses a recent change made in error, which took effect November 5, 1997.
Mercury (aryl and inorganic) (as Hg) PEL is changed from 0.1 mg/m3 TWA to 0.1 mg/m3 ceiling limit which makes this PEL identical to OSHA's rule (Code of Federal Regulations 1910.1000 Table Z-1 and Z-2) and provides appropriate protection of the health of workers where these chemicals are used.
The following state-initiated amendments do not establish additional compliance requirements.
A skin designation is added to carbon tetrachloride to make it consistent with the health data. This will not establish additional compliance requirements because of the current personal protective equipment requirements for use of carbon tetrachloride.
A new note is added for all respirable fraction PELs to reflect the current ACGIH definition of respirable fraction.
A new entry for arsenic, inorganic compounds (as As) PEL is added to include the 10 ug/m3 PEL found in WAC 296-62-07347 Inorganic arsenic standard for all uses covered by WAC 296-62-07347. This does not replace the existing PEL for arsenic, inorganic compounds which applies to all uses not covered by WAC 296-62-07347.
Note g/ is deleted to eliminate confusion.
Other minor amendments are made to correct typographical errors, correct errors in references, delete duplicate lines, correct lettering in notes and improve the clarity of information presented.
WAC 296-62-07477 Appendix C--Questions and answers (appendix to methylene chloride standard located in Part G of chapter 296-62 WAC, General occupational health standards), state-initiated amendments remove the word "Solution" from Figure 2. This is a minor correction that does not establish additional compliance requirements.
Citation of Existing Rules Affected by this Order: Amending WAC 296-62-07477 Appendix C and WAC 296-62-07515 Control of chemical agents.
Statutory Authority for Adoption: RCW 49.17.040, [49.17].050, [49.17].060.
Adopted under notice filed as WSR 98-05-061 on February 16, 1998.
Changes Other than Editing from Proposed to Adopted Version: WAC 296-62-07515 Control of chemical agents, the following minor changes were made to the final rule to make the permissible exposure limit (PEL) table easier to use. None of these changes represents a substantive change to either the existing standard or the standard as proposed in the proposed standard as published in the Washington State Register.
1. A second listing is added to the table to "Arsenic, inorganic compounds" reflecting the existing 10 µg/m3 PEL requirement from WAC 296-62-07347 Inorganic arsenic. The existing PEL in the table would remain in place and would continue to apply to the exceptions to WAC 296-62-07347.
2. Duplicate PEL information is deleted for:
Silica, amorphous, diatomaceous earth;
Dinitolmide.
3. Note "g/" is deleted. Note "g/" provided the total dust equations for Quartz Silica from the table.
4. Formatting changes are made throughout the table to make the format consistent and correcting typographical errors.
Number of Sections Adopted in Order to Comply with Federal Statute: New 0, amended 0, repealed 0; Federal Rules or Standards: New 0, amended 2, repealed 0; or Recently Enacted State Statutes: New 0, amended 0, repealed 0.
Number of Sections Adopted at Request of a Nongovernmental Entity: New 0, amended 0, repealed 0.
Number of Sections Adopted on the Agency's Own Initiative: New 0, amended 1, repealed 0.
Number of Sections Adopted in Order to Clarify, Streamline, or Reform Agency Procedures: New 0, amended 1, repealed 0.
Number of Sections Adopted Using Negotiated Rule Making: New 0, amended 0, repealed 0; Pilot Rule Making: New 0, amended 0, repealed 0; or Other Alternative Rule Making: New 0, amended 0, repealed 0.
Effective Date of Rule: July 24, 1998.
April 24, 1998
Gary Moore
Director
OTS-1968.1
AMENDATORY SECTION (Amending WSR 97-18-062, filed 9/2/97, effective 12/1/97)
WAC 296-62-07477 Appendix C.
Questions and Answers
Methylene Chloride Control in Furniture Stripping
(Adapted from NIOSH publication No. 93-133)
Introduction
This appendix answers commonly asked questions about the hazards from exposure to methylene chloride. It also describes approaches to controlling methylene chloride exposure during the most common furniture stripping processes. Although these approaches were developed and field tested by the National Institute of Occupational Safety and Health, each setting requires custom installation because of the different air flow interferences at each site.
1. What is the Stripping Solution Base?
The most common active ingredient in paint removers is a chemical called methylene chloride. Methylene chloride is present in the paint remover to penetrate, blister, and finally lift the old finish. Other chemicals in paint removers work to accelerate the stripping process, to retard evaporation, and to act as thickening agents. These other ingredients may include: methanol, toluene, acetone, or paraffin.1
2. Is Methylene Chloride Bad for Me?
Exposure to methylene chloride may cause short-term health effects or long-term health effects.
Short-Term (Acute) Health Effects
Exposure to high levels of paint removers over short periods of time can cause irritation to the skin, eyes, mucous membranes, and respiratory tracts. Other symptoms of high exposure are dizziness, headache, and lack of coordination. The occurrence of any of these symptoms indicates that you are being exposed to high levels of methylene chloride. At the onset of any of these symptoms, you should leave the work area, get some fresh air, and determine why the levels were high.
A portion of inhaled methylene chloride is converted by the body to carbon monoxide, which can lower the blood's ability to carry oxygen. When the solvent is used properly, however, the levels of carbon monoxide should not be hazardous. Individuals with cardiovascular or pulmonary health problems should check with their physician before using the paint stripper. Individuals experiencing severe symptoms such as shortness of breath or chest pains should obtain proper medical care immediately.1
Long-Term (Chronic) Health Effects
Methylene chloride has been shown to cause cancer in certain laboratory animal tests. The available human studies do not provide the necessary information to determine whether methylene chloride causes cancer in humans. However, as a result of the animal studies, methylene chloride is considered a potential occupational carcinogen. There is also considerable indirect evidence to suggest that workers exposed to methylene chloride may be at an increased risk of developing ischemic heart disease. Therefore, it is prudent to minimize exposure to solvent vapors.3
3. What does the Methylene Chloride Standard Require?
On January 10, 1997, the Occupational Safety and Health Administration published a new regulation for methylene chloride. The standard establishes an eight-hour time-weighted average exposure limit of 25 parts per million (ppm), as well as a short-term exposure limit of 125 ppm determined from a 15 minute sampling period. That is a reduction from the current WISHA limit of 100 ppm. The standard also sets a 12.5 ppm action level (a level that would trigger periodic exposure monitoring and medical surveillance provisions).2 WISHA adopted an identical standard on[date].
The National Institute for Occupational Safety and Health recommends that methylene chloride be regarded as a "potential occupational carcinogen." NIOSH further recommends that occupational exposure to methylene chloride be controlled to the lowest feasible limit. This recommendation was based on the observation of cancers and tumors in both rats and mice exposed to methylene chloride in air.5
4. How Can I Be Exposed to Methylene Chloride while Stripping Furniture?
Methylene chloride can be inhaled when vapors are in the air. Inhalation of the methylene chloride vapors is generally the most important source of exposure. Methylene chloride evaporates quicker than most chemicals. The odor threshold of methylene chloride is 300 ppm.6 Therefore, once you smell methylene chloride, you are being over-exposed. Pouring, moving, or stirring the chemical will increase the rate of evaporation.
Methylene chloride can be absorbed through the skin either by directly touching the chemical or through your gloves. Methylene chloride can be swallowed if it gets on your hands, clothes, or beard, or if food or drinks become contaminated.
5. How Can Breathing Exposures be Reduced?
Install a Local Exhaust Ventilation System
Local exhaust ventilation can be used to control exposures. Local exhaust ventilation systems capture contaminated air from the source before it spreads into the workers' breathing zone.7 If engineering controls are not effective, only a self-contained breathing apparatus equipped with a full face piece and operated in a positive-pressure mode or a supplied-air respirator affords the level of protection. Air-purifying respirators such as gas masks with organic vapor canisters can only be used for escape situations.8 These gas masks are not suitable for normal work situations because methylene chloride is poorly absorbed by the canister filtering material.
A local exhaust system consists of the following: a hood, a fan, ductwork, and a replacement air system.9,10,11 Two processes are commonly used in furniture stripping: flow-over and dip tanks. For flow-over systems there are two common local exhaust controls for methylene chloride - a slot hood and a down draft hood. A slot hood of different design is most often used for dip tanks. (See Figures 1, 2, and 3.)
The hood is made of sheet metal and connected to the tank. All designs require a centrifugal fan to exhaust the fumes, ductwork connecting the hood and the fan, and a replacement air system to bring conditioned air into the building to replace the air exhausted.
In constructing or designing a slot or down draft hood, use the following data:
Place illustration here. |
Place illustration here. |
Place illustration here. |
Place illustration here. |
Safe Work Practices
Workers can lower exposures by decreasing their access to the methylene chloride.12
1) Turn on dip tank control system several minutes before entering the stripping area.
2) Avoid unnecessary transferring or moving of the stripping solution.
3) Keep face out of the air stream between the solution-covered furniture and the exhaust system.
4) Keep face out of vapor zone above the stripping solution and the dip tank.
5) Retrieve dropped items with a long handled tool.
6) Keep the solution-recycling system off when not in use. Cover reservoir for recycling system.
7) Cover dip tank when not in use.
8) Provide adequate ventilation for rinse area.
How Can Skin Exposures Be Reduced?
Skin exposures can be reduced by wearing gloves whenever you are in contact with the stripping solution.13
1) Two gloves should be worn. The inner glove should be made from polyethylene/ethylene vinyl alcohol (e.g., Silver Shield®, or 4H®). This material, however, does not provide good physical resistance against tears, so an outer glove made from nitrile or neoprene should be worn.
2) Shoulder-length gloves will be more protective.
3) Change gloves before the break-through time occurs. Rotate several pairs of gloves throughout the day. Let the gloves dry in a warm well ventilated area at least over night before reuse.
4) Keep gloves clean by rinsing often. Keep gloves in good condition. Inspect the gloves before use for pin-holes, cracks, thin spots, and stiffer than normal or sticky surfaces.
5) Wear a face shield or goggles to protect face and eyes.
6. What Other Problems Can Occur?
Stripping Solution Temperature
Most manufacturers of stripping solution recommend controlling the solution to a temperature of 70F. This temperature is required for the wax in the solution to form a vapor barrier on top of the solution to keep the solution from evaporating too quickly. If the temperature is too high, the wax will not form the vapor barrier. If it is too cold, the wax will solidify and separate from the solvent causing increased evaporation. Use a belt heater to heat the solution to the correct temperature. Call your solution manufacturer for the correct temperature for your solution.14
Make-Up Air
Air will enter a building in an amount to equal the amount of air exhausted whether or not provision is made for this replacement. If a local exhaust system is added a make-up or replacement air system must be added to replace the air removed. Without a replacement air system, air will enter the building through cracks causing uncontrollable eddy currents. If the building perimeter is tightly sealed, it will prevent the air from entering and severely decrease the amount exhausted from the ventilation system. This will cause the building to be under negative pressure and decrease the performance of the exhaust system.15
Dilution Ventilation
With general or dilution ventilation, uncontaminated air is moved through the workroom by means of fans or open windows, which dilutes the pollutants in the air. Dilution ventilation does not provide effective protection to other workers and does not confine the methylene chloride vapors to one area.16
Phosgene Poisoning from Use of Kerosene Heaters
Do not use kerosene heaters or other open flame heaters while stripping furniture. Use of kerosene heaters in connection with methylene chloride can create lethal or dangerous concentrations of phosgene. Methylene chloride vapor is mixed with the air used for the combustion of kerosene in kerosene stoves. The vapor thus passes through the flames, coming into close contact with carbon monoxide at high temperatures. Any chlorine formed by decomposition may, under these conditions, react with carbon monoxide and form phosgene.17
references
1Halogenated Solvents Industry Alliance and Consumer Product Safety Commission [1990]. Stripping Paint from Wood (Pamphlet for consumers on how to strip furniture and precautions to take). Washington DC: Consumer Product Safety Commission.
2Ibid.
3NIOSH [1992]. NIOSH Testimony on Occupational Safety and Health Administration's proposed rule on occupational exposure to methylene chloride, September 21, 1992, OSHA Docket No. H-71. NIOSH policy statements. Cincinnati, OH: U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control, National Institute for Occupational Safety and Health.
456 Fed. Reg. 57036 [1991]. Occupational Safety and Health Administration: Proposed rule on occupational exposure to methylene chloride.
5NIOSH [1992].
6Kirk, R.E. and P.F. Othmer, Eds. [1978]. Encyclopedia of Chemical Technology, 3rd Ed., Vol. 5:690. New York: John Wiley & Sons, Inc.
7ACGIH [1988]. Industrial Ventilation: A Manual of Recommended Practice. 20th Ed. Cincinnati, OH: American Conference of Governmental Industrial Hygienists.
8NIOSH [1992].
9Fairfield, C.L. and A.A. Beasley [1991]. In-depth Survey Report at the Association for Retarded Citizens, Meadowlands, PA. The Control of Methylene Chloride During Furniture Stripping. Cincinnati, OH: U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control, National Institute for Occupational Safety and Health.
10Fairfield, C.L. [1991]. In-depth Survey Report at the J.M. Murray Center, Cortland, NY. The Control of Methylene Chloride During Furniture Stripping. Cincinnati, OH: U.S. Department of Health and Human Services, Publish Health Service, Centers for Disease Control, National Institute for Occupational Safety and Health.
11Hall, R.M., K.F. Martinez, and P.A. Jensen [1992]. In-depth Survey Report at Tri-County Furniture Stripping and Refinishing, Cincinnati, OH. The Control of Methylene Chloride During Furniture Stripping. Cincinnati, OH: U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control, National Institute for Occupational Safety and Health.
12Fairfield, C.L. and A.A. Beasley [1991]. In-depth Survey Report at the Association for Retarded Citizens, Meadowlands, PA. The Control of Methylene Chloride During Furniture Stripping. Cincinnati, OH: U.S. Department of Health and Human Service, Centers for Disease Control, National Institute for Occupational Safety and Health.
13Roder, M. [1991]. Memorandum of March 11, 1991 from Michael Roder of the Division of Safety Research to Cheryl L. Fairfield of the Division of Physical Sciences and Engineering, National Institute for Occupational Safety and Health, Centers for Disease Control, Public Health Service, U.S. Department of Health and Human Services.
14Kwick Kleen Industrial Solvents, Inc., [1981]. Operations Manual, Kwick Kleen Industrial Solvents, Inc., Vincennes, IN.
15ACGIH [1988].
16Ibid.
17Gerritsen, W.B. and C.H. Buschmann [1960]. Phosgene Poisoning Caused by the Use of Chemical Paint Removers containing Methylene Chloride in Ill-Ventilated Rooms Heated by Kerosene Stoves. British Journal of Industrial Medicine 17:187.
[Statutory Authority: RCW 49.17.040, [49.17].050 and [49.17].060. 97-18-062, § 296-62-07477, filed 9/2/97, effective 12/1/97.]
Reviser's note: The brackets and enclosed material in the text of the above section occurred in the copy filed by the agency and appear in the Register pursuant to the requirements of RCW 34.08.040.
OTS-1873.3
AMENDATORY SECTION (Amending WSR 97-19-014, filed 9/5/97, effective 11/5/97)
WAC 296-62-07515 Control of chemical agents. Chemical agents shall be controlled in such a manner that the workers exposure shall not exceed the applicable limits in WAC 296-62-075 through 296-62-07515.
TABLE 1: LIMITS FOR AIR CONTAMINANTS
Permissible Exposure Limits (PEL)
TWA | STEL(( |
CEILING | Skin
Designation | |||||
Substance | CAS(( Number |
ppma(( |
ppma(( |
ppma(( |
||||
Abate, see Temephos | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Acetaldehyde | 75-07-0 | 100 | 180 | 150 | 270 | ---- | ---- | ---- |
Acetic acid | 64-19-7 | 10 | 25 | ---- | ---- | ---- | ---- | ---- |
Acetic anhydride | 108-24-7 | ---- | ---- | ---- | ---- | 5.0 | 20 | ---- |
Acetone | 67-64-1 | 750 | 1800 | 1000 | 2400 | ---- | ---- | ---- |
Acetonitrile | 75-05-8 | 40 | 70 | 60 | 105 | ---- | ---- | ---- |
2-Acetylaminofluorene
(see WAC 296-62-073) |
53-96-3 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Acetylene | 74-86-2 | Simple | Asphyxiant | ---- | ---- | ---- | ---- | ---- |
Acetylene dichloride
(see 1,2-Dichloroethylene) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Acetylene tetrabromide | 79-27-6 | 1.0 | 14 | ---- | ---- | ---- | ---- | ---- |
Acetylsalicylic acid
(Aspirin) |
50-78-2 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Acrolein | 107-02-8 | 0.1 | 0.25 | 0.3 | 0.8 | ---- | ---- | ---- |
Acrylamide | 79-06-1 | ---- | 0.03 | ---- | ---- | ---- | ---- | X |
Acrylic acid | 79-10-7 | 10 | 30 | ---- | ---- | ---- | ---- | X |
Acrylonitrile
(see WAC (( 296-62-07336(3)) |
107-13-1 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Aldrin | 309-00-2 | ---- | 0.25 | ---- | ---- | ---- | ---- | X |
Allyl alcohol | 107-18-6 | 2.0 | 5.0 | 4.0 | 10 | ---- | ---- | X |
Allyl Chloride | 107-05-1 | 1.0 | 3.0 | 2.0 | 6.0 | ---- | ---- | ---- |
Allyl glycidyl ether (AGE) | 106-92-3 | 5.0 | 22 | 10 | 44 | ---- | ---- | ---- |
Allyl propyl disulfide | 2179-59-1 | 2.0 | 12 | 3.0 | 18 | ---- | ---- | ---- |
alpha-Alumina
(see Aluminum oxide) |
1344-28-1 | (( |
||||||
Total dust | ---- | 10 | ---- | ---- | ---- | ---- | ---- | |
Respirable fraction | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- | |
Aluminum, metal and
oxide (as Al) |
7429-90-5 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
pyro powders | ---- | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
welding fumes (( |
---- | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
soluble salts | ---- | ---- | 2.0 | ---- | ---- | ---- | ---- | ---- |
alkyls (NOC) | ---- | ---- | 2.0 | ---- | ---- | ---- | ---- | ---- |
Alundum (see Aluminum oxide) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
4-Aminodiphenyl
(see WAC 296-62-073) |
92-67-1 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
2-Aminoethanol
(see Ethanolamine) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
2-Aminopyridine | 504-29-0 | 0.5 | 2.0 | ---- | ---- | ---- | ---- | ---- |
Amitrole | 61-82-5 | ---- | 0.2 | ---- | ---- | ---- | ---- | ---- |
Ammonia | 7664-41-7 | 25 | 18 | 35 | 27 | ---- | ---- | ---- |
Ammonium chloride, fume | 12125-02-9 | ---- | 10 | ---- | 20 | ---- | ---- | ---- |
Ammonium sulfamate (Ammate) | 7773-06-0 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
n-Amyl acetate | 628-63-7 | 100 | 525 | ---- | ---- | ---- | ---- | ---- |
sec-Amyl acetate | 626-38-0 | 125 | 650 | ---- | ---- | ---- | ---- | ---- |
Aniline and homologues | 62-53-3 | 2.0 | 8.0 | ---- | ---- | ---- | ---- | X |
Anisidine (o, p-isomers) | 29191-52-4 | 0.1 | 0.5 | ---- | ---- | ---- | ---- | X |
Anitmony and Compounds (as Sb) | 7440-36-0 | ---- | 0.5 | ---- | ---- | ---- | ---- | ---- |
ANTU
(alpha Naphthyl thiourea) |
86-88-4 | ---- | 0.3 | ---- | ---- | ---- | ---- | ---- |
Argon | 7440-37-1 | Simple | Asphyxiant | ---- | ---- | ---- | ---- | ---- |
Arsenic,
Organic compounds (as As) |
7440-38-2 | ---- | 0.2 | ---- | ---- | ---- | ---- | ---- |
Arsenic, Inorganic
compounds (as As) (when use is covered by WAC 296-62-07347) |
7440-38-2 | ---- | 0.01 | ---- | ---- | ---- | ---- | ---- |
Arsenic, Inorganic
compounds(( ((( covered by WAC 296-62-07347 (( |
7440-38-2 | ---- | 0.2 | ---- | ---- | ---- | ---- | ---- |
Arsine | 7784-42-1 | 0.05 | 0.2 | ---- | ---- | ---- | ---- | ---- |
Asbestos
(see WAC 296-62-077 through 296-62-07753) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Asphalt (Petroleum fumes) | 8052-42-4 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Atrazine | 1912-24-9 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Azinphos methyl | 86-50-0 | ---- | 0.2 | ---- | ---- | ---- | ---- | X |
Barium, soluble
compounds (as Ba) |
7440-39-3 | ---- | 0.5 | ---- | ---- | ---- | ---- | ---- |
Barium Sulfate | 7727-43-7 | (( |
||||||
Total dust | ---- | ---- | 10.0 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Benomyl | 17804-35-2 | (( |
||||||
Total dust | ---- | 0.8 | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Benzene(( (see WAC 296-62-07523)(( |
71-43-2 | 1.0 | ---- | 5.0 | ---- | ---- | ---- | ---- |
Benzidine(( (see WAC 296-62-073) |
92-87-5 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
(( (see Quinone) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Benzo(a) pyrene(( (see Coal tar pitch volatiles) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Benzoyl peroxide | 94-36-0 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Benzyl chloride | 100-44-7 | 1.0 | 5.0 | ---- | ---- | ---- | ---- | ---- |
Beryllium and beryllium
compounds (as Be) |
7440-41-7 | --- | 0.002 | --- | 0.005
(30 min.) |
---- | 0.025 | --- |
Biphenyl (see Diphnyl) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Bismuth telluride, Undoped | 1304-82-1 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Bismuth telluride, Se-doped | ---- | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Borates, tetra, sodium salts(( |
||||||||
Anhydrous | 1330-43-4 | ---- | 1.0 | ---- | ---- | ---- | ---- | ---- |
Decahydrate | 1303-96-4 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Pentahydrate | 12179-04-3 | ---- | 1.0 | ---- | ---- | ---- | ---- | ---- |
Boron oxide | 1303-86-2 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Boron tribromide | 10294-33-4 | ---- | ---- | ---- | ---- | 1.0 | 10 | ---- |
Boron trifluoride | 7637-07-2 | ---- | ---- | ---- | ---- | 1.0 | 3.0 | ---- |
Bromacil | 314-40-9 | 1.0 | 10 | ---- | ---- | ---- | ---- | ---- |
Bromine | 7726-95-6 | 0.1 | 0.7 | 0.3 | 2.0 | ---- | ---- | ---- |
Bromine pentafluoride | 7789-30-2 | 0.1 | 0.7 | ---- | ---- | ---- | ---- | ---- |
Bromochloromethane(( (see Chlorobromethane) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Bromoform | 15-25-2 | 0.5 | 5.0 | ---- | ---- | ---- | ---- | X |
Butadiene
(1,3-butadiene) |
106-99-0 | 1 | 2.2 | 5 | ---- | ---- | ---- | ---- |
Butane | 106-97-8 | 800 | 1,900 | ---- | ---- | ---- | ---- | ---- |
Butanethiol
(see Butyl mercaptan) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
2-Butanone
(Methyl ethyl ketone) |
78-93-3 | 200 | 590 | 300 | 885 | ---- | ---- | ---- |
2-Butoxy ethanol
(Butyl Cellosolve) |
111-76-2 | 25 | 120 | ---- | ---- | ---- | ---- | X |
n-Butyl acetate | 123-86-4 | 150 | 710 | 200 | 950 | ---- | ---- | ---- |
sec-Butyl acetate | 105-46-4 | 200 | 950 | ---- | ---- | ---- | ---- | ---- |
tert-Butyl acetate | 540-88-5 | 200 | 950 | ---- | ---- | ---- | ---- | ---- |
Butyl acrylate | 141-32-2 | 10 | 55 | ---- | ---- | ---- | ---- | ---- |
n-Butyl alcohol | 71-36-3 | ---- | ---- | ---- | ---- | 50 | 150 | X |
sec-Butyl alcohol | 78-92-2 | 100 | 305 | ---- | ---- | ---- | ---- | ---- |
tert-Butyl alcohol | 75-65-0 | 100 | 300 | 150 | 450 | ---- | ---- | ---- |
Butylamine | 109-73-9 | ---- | ---- | ---- | ---- | 5.0 | 15 | X |
tert-Butyl chromate
(see CrO3) |
1189-85-1 | ---- | ---- | ---- | ---- | ---- | 0.1 | X |
n-Butyl glycidyl ether (BGE) | 2426-08-6 | 25 | 135 | ---- | ---- | ---- | ---- | ---- |
n-Butyl lactate | 138-22-7 | 5.0 | 25 | ---- | ---- | ---- | ---- | ---- |
Butyl mercaptan | 109-79-5 | 0.5 | 1.5 | ---- | ---- | ---- | ---- | ---- |
o-sec-Butylphenol | 89-72-5 | 5.0 | 30 | ---- | ---- | ---- | ---- | X |
p-tert-Butyl-toluene | 98-51-1 | 10 | 60 | 20 | 120 | ---- | ---- | ---- |
Cadmium oxide fume(( (see WAC 296-62-074) |
1306-19-0 | ---- | ---- | ---- | ---- | ---- | -- | ---- |
Cadmium dust and salts (as Cd)
(see WAC 296-62-074) |
7440-43-9 | ---- | --- | ---- | ---- | ---- | ---- | ---- |
Calcium arsenate
(see WAC 296-62-07347) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Calcium carbonate | 1317-65-3 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Calcium cyanamide | 156-62-7 | ---- | 0.5 | ---- | ---- | ---- | ---- | ---- |
Calcium hydroxide | 1305-62-0 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Calcium oxide | 1305-78-8 | ---- | 2.0 | ---- | ---- | ---- | ---- | ---- |
Calcium silicate | 1344-95-2 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Calcium sulfate | 7778-18-9 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Camphor (synthetic) | 76-22-2 | ---- | 2.0 | ---- | ---- | ---- | ---- | ---- |
Caprolactam(( |
105-60-2 | (( |
||||||
Dust | ---- | ---- | 1.0 | ---- | 3.0 | ---- | ---- | ---- |
Vapor | ---- | 5.0 | 20 | 10 | 40 | ---- | ---- | ---- |
Captafol
(Difolatan) |
2425-06-1 | ---- | 0.1 | ---- | ---- | ---- | ---- | X |
Captan | 133-06-2 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Carbaryl (Sevin) | 63-25-2 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Carbofuran (Furadon) | 1563-66-2 | ---- | 0.1 | ---- | ---- | ---- | ---- | ---- |
Carbon black | 1333-86-4 | ---- | 3.5 | ---- | ---- | ---- | ---- | ---- |
Carbon dioxide | 124-38-9 | 5,000 | 9,000 | 30,000 | 54,000 | ---- | ---- | ---- |
Carbon disulfide | 75-15-0 | 4.0 | 12 | 12 | 36 | ---- | ---- | X |
Carbon monoxide | 630-08-0 | 35 | 40 | ---- | ---- | 200 (( |
229 (( |
---- |
Carbon tetrabromide | 558-13-4 | 0.1 | 1.4 | 0.3 | 4.0 | ---- | ---- | ---- |
Carbon tetrachloride | 56-23-5 | 2.0 | 12.6 | ---- | ---- | ---- | ---- | (( |
Carbonyl chloride
(see Phosgene) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Carbonyl fluoride | 353-50-4 | 2.0 | 5.0 | 5.0 | 15 | ---- | ---- | ---- |
Catechol (Pyrocatechol) | 120-80-9 | 5.0 | 20 | ---- | ---- | ---- | ---- | X |
Cellulose (paper fiber) | 9004-34-6 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Cesium hydroxide | 21351-79-1 | ---- | 2.0 | ---- | ---- | ---- | ---- | ---- |
Chlordane | 57-74-9 | ---- | 0.5 | ---- | ---- | ---- | ---- | X |
Chlorinated camphene | 8001-35-2 | ---- | 0.5 | ---- | 1.0 | ---- | ---- | X |
Chlorinated diphenyl oxide | 55720-99-5 | ---- | 0.5 | ---- | ---- | ---- | ---- | ---- |
Chlorine | 7782-50-5 | 0.5 | 1.5 | 1.0 | 3.0 | 1.0 | 3.0 | ---- |
Chlorine dioxide | 10049-04-4 | 0.1 | 0.3 | 0.3 | 0.9 | ---- | ---- | ---- |
Chlorine trifluoride | 7790-91-2 | ---- | ---- | ---- | ---- | 0.1 | 0.4 | ---- |
Chloroacetaldehyde | 107-20-0 | ---- | ---- | ---- | ---- | 1.0 | 3.0 | ---- |
a-Chloroacetophenone
(Phenacyl chloride) |
532-21-4 | 0.05 | 0.3 | ---- | ---- | ---- | ---- | ---- |
Chloroacetyl chloride | 79-04-9 | 0.05 | 0.2 | ---- | ---- | ---- | ---- | ---- |
Chlorobenzene
(Monochlorobenzene) |
108-90-7 | 75 | 350 | ---- | ---- | ---- | ---- | ---- |
o-Chlorobenzylidene
malononitrile (OCBM) |
2698-41-1 | ---- | ---- | ---- | ---- | 0.05 | 0.4 | X |
Chlorobromomethane | 74-97-5 | 200 | 1,050 | ---- | ---- | ---- | ---- | ---- |
2-Chloro-1, 3-butadiene
(see beta-Chloroprene) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Chlorodifluoromethane | 75-45-6 | 1,000 | 3,500 | ---- | ---- | ---- | ---- | ---- |
Chlorodiphenyl
(42% Chlorine) (PCB) |
53469-21-9 | ---- | 1.0 | ---- | ---- | ---- | ---- | X |
Chlorodiphenyl
(54% Chlorine) (PCB) |
11097-69-1 | ---- | 0.5 | ---- | ---- | ---- | ---- | X |
1-Chloro-2, 3-epoxypropane(( (see Epichlorhydrin) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
2-Chloroethanol
(see Ethylene chlorohydrin) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Chloroethylene
(see vinyl chloride) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Chloroform (Trichloromethane) | 67-66-3 | 2.0 | 9.78 | ---- | ---- | ---- | ---- | ---- |
1-Chloro-1-nitropropane | 600-25-9 | 2.0 | 10 | ---- | ---- | ---- | ---- | ---- |
bis-Chloromethyl ether
(see WAC 296-62-073) |
542-88-1 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Chloromethyl methyl ether
(see Methyl carbomethyl ether) |
107-30-2 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Chloropentafluoroethane | 76-15-3 | 1,000 | 6,320 | ---- | ---- | ---- | ---- | ---- |
Chloropicrin | 76-06-2 | 0.1 | 0.7 | ---- | ---- | ---- | ---- | ---- |
beta-Chloroprene | 126-99-8 | 10 | 35 | ---- | ---- | ---- | ---- | X |
o-Chlorostyrene | 2039-87-4 | 50 | 285 | 75 | 428 | ---- | ---- | ---- |
o-Chlorotoluene | 95-49-8 | 50 | 250 | ---- | ---- | ---- | ---- | ---- |
2-Chloro-6-trichloromethyl
pyridine (see Nitrapyrin) |
1929-82-4 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Chlorpyrifos | 2921-88-2 | ---- | 0.2 | ---- | ---- | ---- | ---- | X |
Chromic acid and chromates
(as CrO3) |
Varies (( |
---- | (( ---- |
---- | ---- | ---- | (( 0.1 |
---- |
Chromium, sol, chromic,
chromous salts (as Cr) |
7440-47-3 |
---- |
0.5 |
---- |
---- |
---- |
---- |
---- |
Chromium (VI) compounds
(as Cr) |
---- | ---- | 0.05 | ---- | ---- | ---- | ---- | ---- |
Chromium Metal
and insoluble salts |
7440-47-3 |
---- |
0.5 |
---- |
---- |
---- |
---- |
---- |
Chromyl chloride | 14977-61-8 | 0.025 | 0.15 | ---- | ---- | ---- | ---- | ---- |
Chrysene(( pitch volatiles) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Clopidol | 2971-90-6 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Coal dust (less than 5% SiO2)
Respirable fraction |
---- | ---- | 2.0g | ---- | ---- | ---- | ---- | ---- |
Coal dust (greater than or
equal to 5% SiO2) Respirable fraction |
---- | ---- | 0.1g | ---- | ---- | ---- | ---- | ---- |
Coal tar pitch volatiles
(benzene soluble fraction anthracene, BaP, phenanthrene, acridine, chrysene, pyrene) |
65996-93-2 | ---- | 0.2 | ---- | ---- | ---- | ---- | ---- |
Cobalt, metal fume & dust(( (as Co) |
7440-48-4 | ---- | 0.05 | ---- | ---- | ---- | ---- | ---- |
Cobalt carbonyl (as Co) | 10210-68-1 | ---- | 0.1 | ---- | ---- | ---- | ---- | ---- |
Cobalt hydrocarbonyl (as Co) | 16842-03-8 | ---- | 0.1 | ---- | ---- | ---- | ---- | ---- |
Coke oven emissions
(see WAC 296-62-200) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Copper fume
(as Cu) |
7440-50-8 | ---- | 0.1 | ---- | ---- | ---- | ---- | ---- |
Dusts and mists (as Cu) | ---- | ---- | 1.0 | ---- | ---- | ---- | ---- | ---- |
Cotton dust (raw)(( |
---- | ---- | 1.0 | ---- | ---- | ---- | ---- | ---- |
Corundum(( |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Crag herbicide (Sesone) | 136-78-7 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Cresol (all isomers) | 1319-77-3 | 5.0 | 22 | ---- | ---- | ---- | ---- | X |
Crotonaldehyde
|
123-73-9;
4170-30-3 |
2.0 | 6.0 | ---- | ---- | ---- | ---- | ---- |
Crufomate | 299-86-5 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Cumene | 98-82-8 | 50 | 245 | ---- | ---- | ---- | ---- | X |
Cyanamide | 420-04-2 | ---- | 2.0 | ---- | ---- | ---- | ---- | ---- |
Cyanide (as CN) | Varies with Compound | ---- | 5.0 | ---- | ---- | ---- | ---- | X |
Cyanogen | 460-19-5 | 10 | 20 | ---- | ---- | ---- | ---- | ---- |
Cyanogen chloride | 506-77-4 | ---- | ---- | ---- | ---- | 0.3 | 0.6 | ---- |
Cyclohexane | 110-82-7 | 300 | 1,050 | |||||
Cyclohexanol | 108-93-0 | 50 | 200 | ---- | ---- | ---- | ---- | X |
Cyclohexanone | 108-94-1 | 25 | 100 | ---- | ---- | ---- | ---- | X |
Cyclohexene | 110-83-8 | 300 | 1,015 | ---- | ---- | ---- | ---- | ---- |
Cyclohexylamine | 108-91-8 | 10 | 40 | ---- | ---- | ---- | ---- | ---- |
Cyclonite (see RDX) | 121-82-4 | ---- | 1.5 | ---- | ---- | ---- | ---- | X |
Cyclopentadiene | 542-92-7 | 75 | 200 | ---- | ---- | ---- | ---- | ---- |
Cyclopentane | 287-92-3 | 600 | 1,720 | ---- | ---- | ---- | ---- | ---- |
Cyhexatin | 13121-70-5 | ---- | 5.0 | |||||
2,4-D (Dichlorophenoxy-
acetic acid) |
94-75-7 | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
DDT (Dichlorodiphenyltri-
chloroethane) |
50-29-3 | ---- | 1.0 | ---- | ---- | ---- | ---- | X |
DDVP, Dichlorvos | 62-73-7 | 0.1 | 1.0 | ---- | ---- | ---- | ---- | X |
Decaborane | 17702-41-9 | 0.05 | 0.3 | 0.15 | 0.9 | ---- | ---- | X |
Demeton | 8065-48-3 | 0.01 | 0.1 | ---- | ---- | ---- | ---- | X |
Diacetone alcohol
(4-hydroxy-4-methyl- 2-pentanone) |
123-42-2 | 50 | 240 | ---- | ---- | ---- | ---- | ---- |
1, 2-Diaminoethane
(see Ethylenediamine) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Diazinon | 333-41-5 | ---- | 0.1 | ---- | ---- | ---- | ---- | X |
Diazomethane | 334-88-3 | 0.2 | 0.4 | ---- | ---- | ---- | ---- | ---- |
Diborane | 19287-45-7 | 0.1 | 0.1 | ---- | ---- | ---- | ---- | ---- |
Dibrom(( |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
1, 2-Dibromo-3-chloropropane
(DBCP) (see WAC (( 296-62-07342) |
96-12-8 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
2-N-Dibutylamino ethanol | 102-81-8 | 2.0 | 14 | ---- | ---- | ---- | ---- | X |
Dibutyl phosphate | 107-66-4 | 1.0 | 5.0 | 2.0 | 10 | ---- | ---- | ---- |
Dibutyl phthalate | 84-74-2 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Dichloroacetylene | 7572-29-4 | ---- | ---- | ---- | ---- | 0.1 | 0.4 | ---- |
o-Dichlorobenzene | 95-50-1 | ---- | ---- | ---- | ---- | 50 | 300 | ---- |
p-Dichlorobenzene | 106-46-7 | 75 | 450 | 110 | 675 | ---- | ---- | ---- |
3, 3'-Dichlorobenzidine
(see WAC 296-62-073) |
91-94-1 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Dichlorodifluoromethane | 75-71-8 | 1,000 | 4,950 | ---- | ---- | ---- | ---- | ---- |
1, 3-Dichloro-5, 5-dimethyl
hydantoin |
118-52-5 | ---- | 0.2 | ---- | 0.4 | ---- | ---- | ---- |
1, 1-Dichloroethane | 75-34-3 | 100 | 400 | ---- | ---- | ---- | ---- | ---- |
1, 2-Dichloroethane
(see Ethylene dichloride) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
1, 2-Dichloroethylene | 540-59-0 | 200 | 790 | ---- | ---- | ---- | ---- | ---- |
1, 1-Dichloroethylene
(see Vinylidene chloride) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Dichloroethyl ether | 111-44-4 | 5.0 | 30 | 10 | 60 | ---- | ---- | X |
Dichlorofluoromethane | 75-43-4 | 10 | 40 | ---- | ---- | ---- | ---- | ---- |
Dichloromethane
(see Methylene chloride) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
1, 1-Dichloro-1-nitroethane | 594-72-9 | 2.0 | 10. | 10. | ---- | ---- | ---- | ---- |
1, 2-Dichloropropane
(see Propylene dichloride) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Dichloropropene | 542-75-6 | 1.0 | 5.0 | ---- | ---- | ---- | ---- | X |
2, 2-Dichloropropionic acid | 75-99-0 | 1.0 | 6.0 | ---- | ---- | ---- | ---- | ---- |
Dichlorotetrafluoroethane | 76-14-2 | 1,000 | 7,000 | ---- | ---- | ---- | ---- | ---- |
Dichlorvos (DDVP) | 62-73-7 | 0.1 | 1.0 | ---- | ---- | ---- | ---- | X |
Dicrotophos | 141-66-2 | ---- | 0.25 | ---- | ---- | ---- | ---- | X |
Dicyclopentadiene | 77-73-6 | 5.0 | 30 | ---- | ---- | ---- | ---- | ---- |
Dicyclopentadienyl iron | 102-54-5 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Dieldrin | 60-57-1 | ---- | 0.25 | ---- | ---- | ---- | ---- | X |
Diethanolamine | 111-42-2 | 3.0 | 15 | ---- | ---- | ---- | ---- | ---- |
Diethylamine | 109-89-7 | 10 | 30 | 25 | 75 | ---- | ---- | ---- |
2-Diethylaminoethanol | 100-37-8 | 10 | 50 | ---- | ---- | ---- | ---- | X |
Diethylene triamine | 111-40-0 | 1.0 | 4.0 | ---- | ---- | ---- | ---- | X |
Diethyl ether (see Ethyl ether) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Diethyl ketone | 96-22-0 | 200 | 705 | ---- | ---- | ---- | ---- | ---- |
Diethyl phthalate | 84-66-2 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Difluorodibromomethane | 75-61-6 | 100 | 860 | ---- | ---- | ---- | ---- | ---- |
Diglycidyl ether (DGE) | 2238-07-5 | 0.1 | 0.5 | ---- | ---- | ---- | ---- | ---- |
Dihydroxybenzene
(see Hydroquinone) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Diisobutyl ketone | 108-83-8 | 25 | 150 | ---- | ---- | ---- | ---- | ---- |
Diisopropylamine | 108-18-9 | 5.0 | 20 | ---- | ---- | ---- | ---- | X |
Dimethoxymethane (see Methylal) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Dimethyl acetamide | 127-19-5 | 10 | 35 | ---- | ---- | ---- | ---- | X |
Dimethylamine | 124-40-3 | 10 | 18 | ---- | ---- | ---- | ---- | ---- |
4-Dimethylaminoazobenzene
(see WAC 296-62-073) |
60-11-7 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Dimethylaminobenzene
(see Xylidene) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Dimethylaniline
(N, N-Dimethylaniline) |
121-69-7 | 5.0 | 25 | 10 | 50 | ---- | ---- | X |
Dimethylbenzene (see Xylene) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Dimethyl-1, 2-dibromo-2,
2-dichloroethyl phosphate (see Naled) |
300-76-5 | ---- | 3.0 | ---- | ---- | ---- | ---- | X |
Dimethylformamide | 68-12-2 | 10 | 30 | ---- | ---- | ---- | ---- | X |
2, 6-Dimethylheptanone
(see Diisobutyl ketone) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
1, 1-Dimethylhydrazine | 57-14-7 | 0.5 | 1.0 | ---- | ---- | ---- | ---- | X |
Dimethyl phthalate | 131-11-3 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Dimethyl sulfate | 77-78-1 | 0.1 | 0.5 | ---- | ---- | ---- | ---- | X |
Dinitolmide | 148-01-6 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
(3, 5-Dinitro-o-toluamide) | (( |
|||||||
Dinitrobenzene (all isomers) | (alpha)
528-29-0;
(meta) 99-65-0; (para) 100-25-4 |
0.15 | 1.0 | ---- | ---- | ---- | ---- | X |
Dinitro-o-cresol | 534-52-1 | ---- | 0.2 | ---- | ---- | ---- | ---- | X |
Dinitrotoluene | 25321-14-6 | ---- | 1.5 | ---- | ---- | ---- | ---- | X |
Dioxane (Diethylene dioxide) | 123-91-1 | 25 | 90 | ---- | ---- | ---- | ---- | X |
Dioxathion | 78-34-2 | ---- | 0.2 | ---- | ---- | ---- | ---- | X |
Diphenyl (Biphenyl) | 92-52-4 | 0.2 | 1.0 | ---- | ---- | ---- | ---- | ---- |
Diphenylamine | 122-39-4 | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Diphenylmethane diisocyanate
(see Methylene bisphenyl isocyanate (MDI)) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Dipropylene glycol methyl ether | 34590-94-8 | 100 | 600 | 150 | 900 | ---- | ---- | X |
Dipropyl ketone | 123-19-3 | 50 | 235 | ---- | ---- | ---- | ---- | ---- |
Diquat | 85-00-7 | ---- | 0.5 | ---- | ---- | ---- | ---- | ---- |
Di-sec, Octyl phthalate
(Di-2-ethylhexylphthalate) |
117-81-7 | ---- | 5.0 | ---- | 10 | ---- | ---- | ---- |
Disulfram | 97-77-8 | ---- | 2.0 | ---- | ---- | ---- | ---- | ---- |
Disulfoton | 298-04-4 | ---- | 0.1 | ---- | ---- | ---- | ---- | X |
2, 6-Di-tert-butyl-p-cresol | 128-37-0 | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Diuron | 330-54-1 | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Divinyl benzene | 1321-74-0 | 10 | 50 | ---- | ---- | ---- | ---- | ---- |
Emery | 12415-34-8 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Endosulfan (Thiodan) | 115-29-7 | ---- | 0.1 | ---- | ---- | ---- | ---- | X |
Endrin | 72-20-8 | ---- | 0.1 | ---- | ---- | ---- | ---- | X |
Epichlorhydrin | 106-89-8 | 2.0 | 8.0 | ---- | ---- | ---- | ---- | X |
EPN | 2104-64-5 | ---- | 0.5 | ---- | ---- | ---- | ---- | X |
1, 2-Epoxypropane
(see Propylene oxide) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
2, 3-Epoxy-1-propanol
(see Glycidol) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Ethane | ---- | Simple | Asphyxiant | ---- | ---- | ---- | ---- | ---- |
Ethanethiol
(see Ethyl mercaptan) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Ethanolamine | 141-43-5 | 3.0 | 8.0 | 6.0 | 15 | ---- | ---- | ---- |
Ethion | 563-12-2 | ---- | 0.4 | ---- | ---- | ---- | ---- | X |
2-Ethoxyethanol | 110-80-5 | 5.0 | 19 | ---- | ---- | ---- | ---- | X |
2-Ethoxyethyl acetate
(Cellosolve acetate) |
111-15-9 | 5.0 | 27 | ---- | ---- | ---- | ---- | X |
Ethyl acetate | 141-78-6 | 400 | 1,400 | ---- | ---- | ---- | ---- | ---- |
Ethyl acrylate | 140-88-5 | 5.0 | 20 | 25 | 100 | ---- | ---- | X |
Ethyl alcohol (ethanol) | 64-17-5 | 1,000 | 1,900 | ---- | ---- | ---- | ---- | ---- |
Ethylamine | 75-04-07 | 10 | 18 | ---- | ---- | ---- | ---- | ---- |
Ethyl amyl ketone
(5-Methyl-3-hepatone) |
541-85-5 | 25 | 130 | ---- | ---- | ---- | ---- | ---- |
Ethyl benzene | 100-41-4 | 100 | 435 | 125 | 545 | ---- | ---- | ---- |
Ethyl bromide | 74-96-4 | 200 | 890 | 250 | 1,110 | ---- | ---- | ---- |
Ethyl butyl ketone
(3-Heptanone) |
106-35-4 | 50 | 230 | ---- | ---- | ---- | ---- | ---- |
Ethyl chloride | 75-00-3 | 1,000 | 2,600 | ---- | ---- | ---- | ---- | ---- |
Ethylene | 74-85-1 | Simple | Asphyxiant | ---- | ---- | ---- | ---- | ---- |
Ethylene chlorohydrin | 107-07-3 | ---- | ---- | ---- | ---- | 1.0 | 3.0 | X |
Ethylenediamine | 107-15-3 | 10 | 25 | ---- | ---- | ---- | ---- | X |
Ethylene dibromide | 106-93-4 | 0.1 | ---- | 0.5 | ---- | ---- | ---- | ---- |
Ethylene dichloride | 107-06-2 | 1.0 | 4.0 | 2.0 | 8.0 | ---- | ---- | ---- |
Ethylene glycol | 107-21-1 | ---- | ---- | ---- | ---- | 50 | 125 | ---- |
Ethylene glycol dinitrate | 628-96-6 | ---- | ---- | ---- | 0.1 | ---- | ---- | X |
Ethylene glycol monomethyl ether
acetate (Methyl cellosolve acetate) |
---- | 5.0 | 24 | ---- | ---- | ---- | ---- | X |
Ethyleneimine
(see WAC 296-62-073) |
151-56-4 | ---- | ---- | ---- | ---- | ---- | ---- | X |
Ethylene oxide
(see WAC (( 296-62-07359) |
75-21-8 | 1.0 | 2.0 | ---- | ---- | ---- | ---- | ---- |
Ethyl ether | 60-29-7 | 400 | 1,200 | 500 | 1,500 | ---- | ---- | ---- |
Ethyl formate | 109-94-4 | 100 | 300 | ---- | ---- | ---- | ---- | ---- |
Ethylidine chloride
(see 1, 1-Dichloroethane) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Ethylidene norbornene | 16219-75-3 | ---- | ---- | ---- | ---- | 5.0 | 25 | ---- |
Ethyl mercaptan | 75-08-1 | 0.5 | 1.0 | ---- | ---- | ---- | ---- | ---- |
n-Ethylmorpholine | 100-74-3 | 5.0 | 23 | ---- | ---- | ---- | ---- | X |
Ethyl sec-amyl ketone
(5-methyl-3-heptanone) |
---- | 25 | 130 | ---- | ---- | ---- | ---- | ---- |
Ethyl silicate | 78-10-4 | 10 | 85 | ---- | ---- | ---- | ---- | ---- |
Fenamiphos | 22224-92-6 | ---- | 0.1 | ---- | ---- | ---- | ---- | X |
Fensulfothion (Dasanit) | 115-90-2 | ---- | 0.1 | ---- | ---- | ---- | ---- | ---- |
Fenthion | 55-38-9 | ---- | 0.2 | ---- | ---- | ---- | ---- | X |
Ferbam | 14484-64-1 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Ferrovanadium dust | 12604-58-9 | ---- | 1.0 | ---- | 3.0 | ---- | ---- | ---- |
Fluorides (as F) | Varies (( |
---- | 2.5 | ---- | ---- | ---- | ---- | ---- |
Fluorine | 7782-41-4 | 0.1 | 0.2 | ---- | ---- | ---- | ---- | ---- |
Fluorotrichloromethane
(see Trichlorofluoro methane) |
75-69-4 | ---- | ---- | ---- | ---- | 1,000 | 5,600 | ---- |
Fonofos | 944-22-9 | ---- | 0.1 | ---- | ---- | ---- | ---- | X |
Formaldehyde
(see WAC 296-62-07540) |
50-00-0 | 0.75 | ---- | 2.0 | ---- | ---- | ---- | ---- |
Formamide | 75-12-7 | 20 | 30 | 30 | 45 | ---- | ---- | ---- |
Formic acid | 64-18-6 | 5.0 | 9.0 | ---- | ---- | ---- | ---- | ---- |
Furfural | 98-01-1 | 2.0 | 8.0 | ---- | ---- | ---- | ---- | X |
Furfuryl alcohol | 98-00-0 | 10 | 40 | 15 | 60 | ---- | ---- | X |
Gasoline | 8006-61-9 | 300 | 900 | 500 | 1,500 | ---- | ---- | ---- |
Germanium tetrahydride | 7782-65-2 | 0.2 | 0.6 | ---- | ---- | ---- | ---- | ---- |
Glass, fibrous or dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Gluteraldehyde | 111-30-8 | ---- | ---- | ---- | ---- | 0.2 | 0.8 | ---- |
Glycerin mist | 56-81-5 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Glycidol
(2, 3-Epoxy-1-propanol) |
556-52-5 | 25 | 75 | ---- | ---- | ---- | ---- | ---- |
Glycol monoethyl ether
(see 2-Ethoxyethanol) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Grain dust (oat, wheat, barley) | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Graphite, natural | 7782-42-5 | (( |
||||||
Respirable dust | ---- | ---- | 2.5k | ---- | ---- | ---- | ---- | ---- |
Graphite, Synthetic | (( |
|||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Guthion
(see Azinphosmethyl) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Gypsum | 13397-24-5 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Hafnium | 7440-58-6 | ---- | 0.5 | ---- | ---- | ---- | ---- | ---- |
Helium | ---- | Simple | Asphyxiant | ---- | ---- | ---- | ---- | ---- |
Heptachlor | 76-44-8 | ---- | 0.5 | ---- | ---- | ---- | ---- | X |
Heptane (n-heptane) | 142-82-5 | 400 | 1,600 | 500 | 2,000 | ---- | ---- | ---- |
2-Heptanone(( (see Methyl n-amyl ketone) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
3-Heptanone
(see Ethyl butyl ketone) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Hexachlorobutadiene | 87-68-3 | 0.02 | 0.24 | ---- | ---- | ---- | ---- | X |
Hexachlorocyclopentadiene | 77-47-4 | 0.01 | 0.1 | ---- | ---- | ---- | ---- | ---- |
Hexachloroethane | 67-72-1 | 1.0 | 10 | ---- | ---- | ---- | ---- | X |
Hexachloronaphthalene | 1335-87-1 | ---- | 0.2 | ---- | ---- | ---- | ---- | X |
Hexafluoroacetone | 684-16-2 | 0.1 | 0.7 | ---- | ---- | ---- | ---- | X |
Hexane | (( |
|||||||
n-hexane | 110-54-3 | 50 | 180 | ---- | ---- | ---- | ---- | ---- |
other Isomers | Varies (( |
500 | 1,800 | 1,000 | 3,600 | ---- | ---- | ---- |
2-Hexanone
(Methyl-n-butyl ketone) |
591-78-6 | 5.0 | 20 | ---- | ---- | ---- | ---- | ---- |
Hexone
(Methyl isobutyl ketone) |
108-10-1 | 50 | 205 | 75 | 300 | ---- | ---- | ---- |
sec-Hexyl acetate | 108-84-9 | 50 | 300 | ---- | ---- | ---- | ---- | ---- |
Hexylene Glycol | 107-41-5 | ---- | ---- | ---- | ---- | 25 | 125 | ---- |
Hydrazine | 302-01-2 | 0.1 | 0.1 | ---- | ---- | ---- | ---- | X |
Hydrogen | ---- | Simple | Asphyxiant | ---- | ---- | ---- | ---- | ---- |
Hydrogenated terphenyls | 61788-32-7 | 0.5 | 5.0 | ---- | ---- | ---- | ---- | ---- |
Hydrogen bromide | 10035-10-6 | ---- | ---- | ---- | ---- | 3.0 | 10 | ---- |
Hydrogen chloride | 7647-01-0 | ---- | ---- | ---- | ---- | 5.0 | 7.0 | ---- |
Hydrogen cyanide | 74-90-8 | ---- | ---- | 4.7 | 5.0 | ---- | ---- | X |
Hydrogen fluoride | 7664-39-3 | ---- | ---- | ---- | ---- | 3.0 | 2.5 | ---- |
Hydrogen peroxide | 7722-84-1 | 1.0 | 1.4 | ---- | ---- | ---- | ---- | ---- |
Hydrogen selenide (as Se) | 7783-07-5 | 0.05 | 0.2 | ---- | ---- | ---- | ---- | ---- |
Hydrogen Sulfide | 7783-06-4 | 10 | 14 | 15 | 21 | ---- | ---- | ---- |
Hydroquinone | 123-31-9 | ---- | 2.0 | ---- | ---- | ---- | ---- | ---- |
4-Hydroxy-4-methyl-2-pentanone
(see Diacetone alcohol) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
2-Hydroxypropyl acrylate | 999-61-1 | 0.5 | 3.0 | ---- | ---- | ---- | ---- | X |
Indene | 95-13-6 | 10 | 45 | ---- | ---- | ---- | ---- | ---- |
Indium and compounds (as In) | 7440-74-6 | ---- | 0.1 | ---- | ---- | ---- | ---- | ---- |
Iodine | 7553-56-2 | ---- | ---- | ---- | ---- | 0.1 | 1.0 | ---- |
Iodoform | 75-47-8 | 0.6 | 10 | ---- | ---- | ---- | ---- | ---- |
Iron oxide dust and fume (as Fe) | 1309-37-1 | (( |
||||||
Total particulate | ---- | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Iron pentacarbonyl (as Fe) | 13463-40-6 | 0.1 | 0.8 | 0.2 | 1.6 | ---- | ---- | ---- |
Iron salts, soluble (as Fe) | Varies (( |
---- | 1.0 | ---- | ---- | ---- | ---- | ---- |
Isoamyl acetate | 123-92-2 | 100 | 525 | ---- | ---- | ---- | ---- | ---- |
Isoamyl alcohol
(primary and secondary) |
123-51-3 | 100 | 360 | 125 | 450 | ---- | ---- | ---- |
Isobutyl acetate | 110-19-0 | 150 | 700 | ---- | ---- | ---- | ---- | ---- |
Isobutyl alcohol | 78-83-1 | 50 | 150 | ---- | ---- | ---- | ---- | ---- |
Isooctyl alcohol | 26952-21-6 | 50 | 270 | ---- | ---- | ---- | ---- | X |
Isophorone | 78-59-1 | 4.0 | 23 | ---- | ---- | 5.0 | 25 | ---- |
Isophorone diisocyanate | 4098-71-9 | 0.005 | 0.045 | 0.02 | ---- | ---- | ---- | X |
Isopropoxyethanol | 109-59-1 | 25 | 105 | ---- | ---- | ---- | ---- | ---- |
Isopropyl acetate | 108-21-4 | 250 | 950 | 310 | 1,185 | ---- | ---- | ---- |
Isopropyl alcohol | 67-63-0 | 400 | 980 | 500 | 1,225 | ---- | ---- | ---- |
Isopropylamine | 75-31-0 | 5.0 | 12 | 10 | 24 | ---- | ---- | ---- |
N-Isopropylaniline | 768-52-5 | 2.0 | 10 | ---- | ---- | ---- | ---- | X |
Isopropyl ether | 108-20-3 | 250 | 1,050 | ---- | ---- | ---- | ---- | ---- |
Isopropyl glycidyl ether (IGE) | 4016-14-2 | 50 | 240 | 75 | 360 | ---- | ---- | ---- |
Kaolin | ||||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Ketene | 463-51-4 | 0.5 | 0.9 | 1.5 | 3.0 | ---- | ---- | ---- |
Lead inorganic (as Pb)
(see WAC 296-62-07521) |
7439-92-1 | ---- | 0.05 | ---- | ---- | ---- | ---- | ---- |
Lead arsenate
(see WAC 296-62-07347) |
3687-31-8 | ---- | 0.05 | ---- | ---- | ---- | ---- | ---- |
Lead chromate | 7758-97-6 | ---- | 0.05 | ---- | ---- | ---- | ---- | ---- |
Limestone | 1317-65-3 | |||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Lindane | 58-89-9 | ---- | 0.5 | ---- | ---- | ---- | ---- | X |
Lithium hydride | 7580-67-8 | ---- | 0.025 | ---- | ---- | ---- | ---- | ---- |
L.P.G.
(liquified petroleum gas) |
68476-85-7 | 1,000 | 1,800 | ---- | ---- | ---- | ---- | ---- |
Magnesite | 546-93-0 | |||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Magnesium oxide fume | 1309-48-4 | (( |
||||||
Total particulate | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Malathion | 121-75-5 | |||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | X |
Maleic anhydride | 108-31-6 | 0.25 | 1.0 | ---- | ---- | ---- | ---- | ---- |
Manganese and compound (as Mn) | 7439-96-5 | ---- | ---- | ---- | ---- | ---- | 5.0 | ---- |
Manganese tetroxide and fume
(as Mn) |
7439-96-5 | ---- | 1.0 | ---- | 3.0 | ---- | ---- | ---- |
Manganese cyclopentadienyl
tricarbonyl (as Mn) |
12079-65-1 | ---- | 0.1 | ---- | ---- | ---- | ---- | X |
Manganese tetroxide (as Mn) | 1317-35-7 | ---- | 1.0 | ---- | ---- | ---- | ---- | ---- |
Marble | 1317-65-3 | |||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Mercury (aryl and inorganic)
(as Hg) |
7439-97-6 | ---- | (( ---- |
---- | ---- | ---- | (( 0.1 |
X |
Mercury (organo-alkyl compounds)
(as Hg) |
7439-97-6 | ---- | 0.01 | ---- | 0.03 | ---- | ---- | X |
Mercury (vapor) (as Hg) | 7439-97-6 | ---- | 0.05 | ---- | ---- | ---- | ---- | X |
Mesityl oxide | 141-79-7 | 15 | 60 | 25 | 100 | ---- | ---- | ---- |
Methacrylic acid | 79-41-4 | 20 | 70 | ---- | ---- | ---- | ---- | X |
Methane | ---- | Simple | Asphyxiant | ---- | ---- | ---- | ---- | ---- |
Methanethiol
(see Methyl mercaptan) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Methomyl (lannate) | 16752-77-5 | ---- | 2.5 | ---- | ---- | ---- | ---- | ---- |
Methoxychlor | 72-43-5 | |||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
2-Methoxyethanol
(Methyl cellosolve) |
109-86-4 | 5.0 | 16 | ---- | ---- | ---- | ---- | X |
4-Methoxyphenol | 150-76-5 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Methyl acetate | 79-20-9 | 200 | 610 | 250 | 760 | ---- | ---- | ---- |
Methyl acetylene (propyne) | 74-99-7 | 1,000 | 1,650 | ---- | ---- | ---- | ---- | ---- |
Methyl acetylene-propadiene
mixture (MAPP) |
---- | 1,000 | 1,800 | 1,250 | 2,250 | ---- | ---- | ---- |
Methyl acrylate | 96-33-3 | 10 | 35 | ---- | ---- | ---- | ---- | X |
Methylacrylonitrile | 126-98-7 | 1.0 | 3.0 | ---- | ---- | ---- | ---- | X |
Methylal (Dimethoxy-methane) | 109-87-5 | 1,000 | 3,100 | ---- | ---- | ---- | ---- | ---- |
Methyl alcohol (methanol) | 67-56-1 | 200 | 260 | 250 | 325 | ---- | ---- | X |
Methylamine | 74-89-5 | 10 | 12 | ---- | ---- | ---- | ---- | ---- |
Methyl amyl alcohol
(see Methyl isobutyl carbinol) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Methyl n-amyl ketone
(2-Heptanone) |
110-43-0 | 50 | 235 | ---- | ---- | ---- | ---- | ---- |
N-Methyl aniline
(see Monomethyl aniline) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Methyl bromide | 74-83-9 | 5.0 | 20 | ---- | ---- | ---- | ---- | X |
Methyl butyl ketone
(see 2-Hexanone) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Methyl cellosolve
(see 2-Methoxyethanol) |
109-86-4 | 5.0 | 16 | ---- | ---- | ---- | ---- | X |
Methyl cellosolve acetate
(2-Methoxyethyl acetate) |
110-49-6 | 5.0 | 24 | ---- | ---- | ---- | ---- | X |
Methyl chloride | 74-87-3 | 50 | 105 | 100 | 210 | ---- | ---- | ---- |
Methyl chloroform
(1, 1, 1-trichlorethane) |
71-55-6 | 350 | 1,900 | 450 | 2,450 | ---- | ---- | ---- |
Methyl chloromethyl ether
(see WAC 296-62-073) |
107-30-2 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Methyl 2-cyanoacrylate | 137-05-3 | 2.0 | 8.0 | 4.0 | 16 | ---- | ---- | ---- |
Methylcyclohexane | 108-87-2 | 400 | 1,600 | ---- | ---- | ---- | ---- | ---- |
Methylcyclohexanol | 25639-42-3 | 50 | 235 | ---- | ---- | ---- | ---- | ---- |
Methylcyclohexanone | 583-60-8 | 50 | 230 | 75 | 345 | ---- | ---- | X |
Methylcyclopentadienyl
manganese tricarbonyl (as Mn) |
12108-13-3 | ---- | 0.2 | ---- | ---- | ---- | ---- | X |
Methyl demeton | 8022-00-2 | ---- | 0.5 | ---- | ---- | ---- | ---- | X |
Methylene bisphenyl isocyanate
(MDI) |
101-68-8 | ---- | ---- | ---- | ---- | 0.02 | 0.2 | ---- |
4, 4'-Methylene bis
(2-chloroaniline (MBOCA)) (see WAC 296-62-073) |
101-14-4 | 0.02 | 0.22 | ---- | ---- | ---- | ---- | X |
Methylene bis
(4-cyclohexylisocyanate) |
5124-30-1 | ---- | ---- | ---- | ---- | 0.01 | 0.11 | ---- |
Methylene chloride | 75-09-2 | 100 | ---- | 500 | ---- | ---- | ---- | ---- |
4, 4-Methylene dianiline | 101-77-9 | 0.1 | 0.8 | ---- | ---- | ---- | ---- | X |
Methyl ethyl ketone (MEK)
(see 2-Butanone) |
78-93-3 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Methyl ethyl ketone peroxide
(MEKP) |
1338-23-4 | ---- | ---- | ---- | ---- | 0.2 | 1.5 | ---- |
Methyl formate | 107-31-3 | 100 | 250 | 150 | 375 | ---- | ---- | ---- |
5-Methyl-3-heptanone
(see Ethyl amyl ketone) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Methyl hydrazine
(see Monomethyl hydrazine) |
60-34-4 | ---- | ---- | ---- | ---- | 0.2 | 0.35 | X |
Methyl iodide | 74-88-4 | 2.0 | 10 | ---- | ---- | ---- | ---- | X |
Methyl isoamyl ketone | 110-12-3 | 50 | 240 | ---- | ---- | ---- | ---- | ---- |
Methyl isobutyl carbinol | 108-11-2 | 25 | 100 | 40 | 165 | ---- | ---- | X |
Methyl isobutyl ketone
(see Hexone) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Methyl isocyanate | 624-83-9 | 0.02 | 0.05 | ---- | ---- | ---- | ---- | X |
Methyl isopropyl ketone | 563-80-4 | 200 | 705 | ---- | ---- | ---- | ---- | ---- |
Methyl mercaptan | 74-93-1 | 0.5 | 1.0 | ---- | ---- | ---- | ---- | ---- |
Methyl methacrylate | 80-62-6 | 100 | 410 | ---- | ---- | ---- | ---- | ---- |
Methyl parathion | 298-00-0 | ---- | 0.2 | ---- | ---- | ---- | ---- | X |
Methyl propyl ketone
(see 2-Pentanone) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Methyl silicate | 684-84-5 | 1.0 | 6.0 | ---- | ---- | ---- | ---- | ---- |
alpha-Methyl styrene | 98-83-9 | 50 | 240 | 100 | 485 | ---- | ---- | ---- |
Mevinphos (see Phosdrin) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Metribuzin | 21087-64-9 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Mica (see Silicates) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Molybdenum (as Mo) | 7439-98-7 | (( |
||||||
Soluble compounds | ---- | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Insoluble compounds | ||||||||
Total dust | ---- | ---- | ---- | 10 | ---- | ---- | ---- | ---- |
Monocrotophos (Azodrin) | 6923-22-4 | ---- | 0.25 | ---- | ---- | ---- | ---- | ---- |
Monomethyl aniline | 100-61-8 | 0.5 | 2.0 | ---- | ---- | ---- | ---- | X |
Monomethyl hydrazine | ---- | ---- | ---- | ---- | ---- | 0.2 | 0.35 | ---- |
Morpholine | 110-91-8 | 20 | 70 | 30 | 105 | ---- | ---- | X |
Naled | 300-76-5 | ---- | 3.0 | ---- | ---- | ---- | ---- | X |
Naphtha (Coal tar) | 8030-30-6 | 100 | 400 | ---- | ---- | ---- | ---- | X |
Naphthalene | 91-20-3 | 10 | 50 | 15 | 75 | ---- | ---- | ---- |
alpha-Naphthylamine
(see WAC 296-62-073) |
134-32-7 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
beta-Naphthylamine
(see WAC 296-62-073) |
91-59-8 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Neon | 7440-01-9 | Simple | Asphyxiant | ---- | ---- | ---- | ---- | ---- |
Nickel carbonyl (as Ni) | 13463-39-3 | 0.001 | 0.007 | ---- | ---- | ---- | ---- | ---- |
(( |
7440-02-0 | |||||||
Metal and insoluble
compounds |
---- | 1.0 | ---- | ---- | ---- | ---- | ---- | |
Soluble compounds | ---- | 0.1 | ---- | ---- | ---- | ---- | ---- | |
Nicotine | 54-11-5 | ---- | 0.5 | ---- | ---- | ---- | ---- | X |
Nitrapyrin
(see 2-Chloro-6 trichloromethyl pyridine) |
1929-82-4 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Total dust | ---- | 10 | ---- | ---- | ---- | ---- | ---- | |
Respirable fraction | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- | |
Nitric acid | 7697-37-2 | 2.0 | 5.0 | 4.0 | 10 | ---- | ---- | ---- |
Nitric oxide | 10102-43-9 | 25 | 30 | ---- | ---- | ---- | ---- | ---- |
p-Nitroaniline | 100-01-6 | ---- | 3.0 | ---- | ---- | ---- | ---- | X |
Nitrobenzene | 98-95-3 | 1.0 | 5.0 | ---- | ---- | ---- | ---- | X |
4-Nitrobiphenyl
(see WAC 296-62-073) |
92-93-3 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
p-Nitrochlorobenzene | 100-00-5 | ---- | 0.5 | ---- | ---- | ---- | ---- | X |
4-Nitrodiphenyl
(see WAC 296-62-073) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Nitroethane | 79-24-3 | 100 | 310 | ---- | ---- | ---- | ---- | ---- |
Nitrogen | 7727-37-9 | Simple | Asphyxiant | ---- | ---- | ---- | ---- | ---- |
Nitrogen dioxide | 10102-44-0 | ---- | ---- | 1.0 | 1.8 | ---- | ---- | ---- |
Nitrogen trifluoride | 7783-54-2 | 10 | 29 | ---- | ---- | ---- | ---- | ---- |
Nitroglycerin | 55-63-0 | ---- | ---- | ---- | 0.1 | ---- | ---- | X |
Nitromethane | 75-52-5 | 100 | 250 | ---- | ---- | ---- | ---- | ---- |
1-Nitropropane | 108-03-2 | 25 | 90 | ---- | ---- | ---- | ---- | ---- |
2-Nitropropane | 79-46-9 | 10 | 35 | ---- | ---- | ---- | ---- | ---- |
N-Nitrosodimethylamine
(see WAC 296-62-073) |
62-75-9 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Nitrotoluene(( |
||||||||
o-isomer | 88-72-2 | 2.0 | 11 | ---- | ---- | ---- | ---- | X |
m-isomer | 98-08-2 | 2.0 | 11 | ---- | ---- | ---- | ---- | X |
p-isomer | 99-99-0 | 2.0 | 11 | ---- | ---- | ---- | ---- | X |
Nitrotirchloromethane
(see Chloropicrin) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Nitrous Oxide
(Nitrogen oxide) |
10024-97-2 | 50 | 90 | ---- | ---- | ---- | ---- | ---- |
Nonane | 111-84-2 | 200 | 1,050 | ---- | ---- | ---- | ---- | ---- |
Octachloronaphthalene | 2234-13-1 | ---- | 0.1 | ---- | 0.3 | ---- | ---- | X |
Octane | 111-65-9 | 300 | 1,450 | 375 | 1,800 | ---- | ---- | ---- |
Oil mist, mineral (particulate) | 8012-95-1 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Osmium tetroxide (as Os) | 20816-12-0 | 0.0002 | 0.002 | 0.0006 | 0.006 | ---- | ---- | ---- |
Oxalic acid | 144-62-7 | ---- | 1.0 | ---- | 2.0 | ---- | ---- | ---- |
Oxygen difluoride | 7783-41-7 | ---- | ---- | ---- | ---- | 0.05 | 0.1 | ---- |
Ozone | 10028-15-6 | 0.1 | 0.2 | 0.3 | 0.6 | ---- | ---- | ---- |
Paraffin wax fume | 8002-74-2 | ---- | 2.0 | ---- | ---- | ---- | ---- | ---- |
Paraquat (Respirable dust) | 4685-14-7 | ---- | 0.1k | ---- | ---- | ---- | ---- | X |
1910-42-5 | ||||||||
2074-50-2 | ||||||||
Parathion | 56-38-2 | ---- | 0.1 | ---- | ---- | ---- | ---- | X |
Particulate polycyclic
aromatic hydrocarbons (see coal tar pitch volatiles) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Particulates not otherwise
regulated (see WAC 296-62-07510) |
(( |
|||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Pentaborane | 19624-22-7 | 0.005 | 0.01 | 0.015 | 0.03 | ---- | ---- | ---- |
Pentachloronaphthalene | 1321-64-8 | ---- | 0.5 | ---- | ---- | ---- | ---- | X |
Pentachlorophenol | 87-86-5 | ---- | 0.5 | ---- | ---- | ---- | ---- | X |
Pentaerythritol | 115-77-5 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Pentane | 109-66-0 | 600 | 1,800 | 750 | 2,250 | ---- | ---- | ---- |
2-Pentanone
(methyl propyl ketone) |
107-87-9 | 200 | 700 | 250 | 875 | ---- | ---- | ---- |
Perchloroethylene
(tetrachloroethylene) |
127-18-4 | 25 | 170 | ---- | ---- | ---- | ---- | ---- |
Perchloromethyl mercaptan | 594-42-3 | 0.1 | 0.8 | ---- | ---- | ---- | ---- | ---- |
Perchloryl fluoride | 7616-94-6 | 3.0 | 14 | 6.0 | 28 | ---- | ---- | ---- |
Perlite | (( |
|||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Petroleum distillates
(Naptha) (Rubber Solvent) |
---- | 100 | 400 | ---- | ---- | ---- | ---- | ---- |
Phenol | 108-95-2 | 5.0 | 19 | ---- | ---- | ---- | ---- | X |
Phenothiazine | 92-84-2 | ---- | 5.0 | ---- | ---- | ---- | ---- | X |
p-Phenylene diamine | 106-50-3 | ---- | 0.1 | ---- | ---- | ---- | ---- | X |
Phenyl ether (vapor) | 101-84-8 | 1.0 | 7.0 | ---- | ---- | ---- | ---- | ---- |
Phenyl ether-diphenyl
mixture (vapor) |
---- | 1.0 | 7.0 | ---- | ---- | ---- | ---- | ---- |
Phenylethylene(( |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Phenyl glycidyl ether (PGE) | 122-60-1 | 1.0 | 6.0 | ---- | ---- | ---- | ---- | ---- |
Phenylhydrazine | 100-63-0 | 5.0 | 20 | 10 | 45 | ---- | ---- | X |
Phenyl mercaptan | 108-98-5 | 0.5 | 2.0 | ---- | ---- | ---- | ---- | ---- |
Phenylphosphine | 638-21-1 | ---- | ---- | ---- | ---- | 0.05 | 0.25 | ---- |
Phorate | 298-02-2 | ---- | 0.05 | ---- | 0.2 | ---- | ---- | X |
Phosdrin (Mevinphos) | 7786-34-7 | 0.01 | 0.1 | 0.03 | 0.3 | ---- | ---- | X |
Phosgene (carbonyl chloride) | 75-44-5 | 0.1 | 0.4 | ---- | ---- | ---- | ---- | ---- |
Phosphine | 7803-51-2 | 0.3 | 0.4 | 1.0 | 1.0 | ---- | ---- | ---- |
Phosphoric acid | 7664-38-2 | ---- | 1.0 | ---- | 3.0 | ---- | ---- | ---- |
Phosphorus (yellow) | 7723-14-0 | ---- | 0.1 | ---- | ---- | ---- | ---- | ---- |
Phosphorous oxychloride | 10025-87-3 | 0.1 | 0.6 | ---- | ---- | ---- | ---- | ---- |
Phosphorus pentachloride | 10026-13-8 | 0.1 | 1.0 | ---- | ---- | ---- | ---- | ---- |
Phosphorus pentasulfide | 1314-80-3 | ---- | 1.0 | ---- | 3.0 | ---- | ---- | ---- |
Phosphorus trichloride | 7719-12-2 | 0.2 | 1.5 | 0.5 | 3.0 | ---- | ---- | ---- |
Phthalic anhydride | 85-44-9 | 1.0 | 6.0 | ---- | ---- | ---- | ---- | ---- |
m-Phthalodinitrile | 626-17-5 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Picloram | 1918-02-1 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Picric acid | 88-89-1 | ---- | 0.1 | ---- | ---- | ---- | ---- | X |
Pindone (( (2-Pivalyl-1, 3-indandione) |
83-26-1 | ---- | 0.1 | ---- | ---- | ---- | ---- | ---- |
Piperazine dihydrochloride | 142-64-3 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Pival (see Pindone) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Plaster of Paris | 26499-65-0 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Platinum (as Pt) | 7440-06-4 | (( |
||||||
Metal | ---- | ---- | 1.0 | ---- | ---- | ---- | ---- | ---- |
Soluble salts | ---- | ---- | 0.002 | ---- | ---- | ---- | ---- | ---- |
Polychlorobiphenyls
(see Chlorodiphenyls) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Portland cement | 65997-15-1 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Potassium hydroxide | 1310-58-3 | ---- | ---- | ---- | ---- | ---- | 2.0 | ---- |
Propane | 74-98-6 | 1,000 | 1,800 | ---- | ---- | ---- | ---- | ---- |
Propargyl alcohol | 107-19-7 | 1.0 | 2.0 | ---- | ---- | ---- | ---- | X |
beta-Propiolactone
(see WAC 296-62-073) |
57-57-8 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Propionic acid | 79-09-4 | 10 | 30 | ---- | ---- | ---- | ---- | ---- |
Propoxur (Baygon) | 114-26-1 | ---- | 0.5 | ---- | ---- | ---- | ---- | ---- |
n-Propyl acetate | 109-60-4 | 200 | 840 | 250 | 1,050 | ---- | ---- | ---- |
n-Propyl alcohol | 71-23-8 | 200 | 500 | 250 | 625 | ---- | ---- | X |
n-Propyl nitrate | 627-13-4 | 25 | 105 | 40 | 170 | ---- | ---- | ---- |
Propylene | ---- | Simple | Asphyxiant | ---- | ---- | ---- | ---- | ---- |
Propylene dichloride
(1, 2-Dichloropropane) |
78-87-5 | 75 | 350 | 110 | 510 | ---- | ---- | ---- |
Propylene glycol dinitrate | 6423-43-4 | 0.05 | 0.3 | ---- | ---- | ---- | ---- | X |
Propylene glycol
monomethyl ether |
107-98-2 | 100 | 360 | 150 | 540 | ---- | ---- | ---- |
Propylene imine | 75-55-8 | 2.0 | 5.0 | ---- | ---- | ---- | ---- | X |
Propylene oxide | 75-56-9 | 20 | 50 | ---- | ---- | ---- | ---- | ---- |
Propyne(( |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Pyrethrum | 8003-34-7 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Pyridine | 110-86-1 | 5.0 | 15 | ---- | ---- | ---- | ---- | ---- |
Quinone | 106-51-4 | 0.1 | 0.4 | ---- | ---- | ---- | ---- | ---- |
RDX (see Cyclonite) | ---- | ---- | 1.5 | ---- | ---- | ---- | ---- | X |
Resorcinol | 108-46-3 | 10 | 45 | 20 | 90 | ---- | ---- | ---- |
Rhodium (as Rh) | 7440-16-6 | |||||||
Insoluble compounds,
Metal fumes and dusts |
---- | ---- | ---- | 0.1 | ---- | ---- | ---- | ---- |
Soluble compounds, salts | ---- | ---- | 0.001 | ---- | ---- | ---- | ---- | ---- |
Ronnel | 299-84-3 | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Rosin core solder, pyrolysis
products (as formaldehyde) |
---- | ---- | 0.1 | ---- | ---- | ---- | ---- | ---- |
Rotenone | 83-79-4 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Rouge | ||||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Rubber solvent (naphtha) | 8002-05-9 | 100 | 400 | ---- | ---- | ---- | ---- | ---- |
Selenium compounds (as Se) | 7782-49-2 | ---- | 0.2 | ---- | ---- | ---- | ---- | ---- |
Selenium hexafluoride (as Se) | 7783-79-1 | 0.05 | 0.2 | ---- | ---- | ---- | ---- | ---- |
Sesone (see Crag herbicide) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Silane (see Silicon tetrahydride) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Silica, amorphous, precipitated
and gel |
112926-00-8 | ---- | 6.0 | ---- | ---- | ---- | ---- | ---- |
Silica, amorphous, diatomaceous
earth, containing less than 1% crystalline silica |
61790-53-2 | (( |
||||||
Total dust | ---- | ---- | 6.0 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 3.0k | ---- | ---- | ---- | ---- | ---- |
Silica, crystalline
cristobalite, respirable dust |
14464-46-1 | ---- | 0.05k | ---- | ---- | ---- | ---- | ---- |
Silica, crystalline
quartz, respirable dust |
14808-60-7 | ---- | 0.1 (( |
---- | ---- | ---- | ---- | ---- |
Silica, crystalline
tripoli (as quartz), respirable dust |
1317-95-9 | ---- | 0.1k | ---- | ---- | ---- | ---- | ---- |
Silica, crystalline
tridymite, respirable dust |
15468-32-3 | ---- | 0.05k | ---- | ---- | ---- | ---- | ---- |
Silica, fused, respirable dust | 60676-86-0 | ---- | 0.1k | ---- | ---- | ---- | ---- | ---- |
Silicates (less than 1% crystalline
silica(( |
||||||||
Mica (Respirable dust) | 12001-26-2 | ---- | 3.0k | ---- | ---- | ---- | ---- | ---- |
Soapstone, Total dust | ---- | ---- | 6.0 | ---- | ---- | ---- | ---- | ---- |
Soapstone, Respirable dust | ---- | ---- | 3.0k | ---- | ---- | ---- | ---- | ---- |
Talc (containing asbestos):
use asbestos limit (see WAC (( 296-62-07705) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Talc (containing no
asbestos), Respirable dust |
14807-96-6 | ---- | 2.0k | ---- | ---- | ---- | ---- | ---- |
Tremolite
(see WAC (( 296-62-07705) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Silicon | 7440-21-3 | |||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Silicon Carbide | 409-21-2 | |||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Silicon tetrahydride | 7803-62-5 | 5.0 | 7.0 | ---- | ---- | ---- | ---- | ---- |
Silver, metal dust and soluble
compounds (as Ag) |
7440-22-4 | ---- | 0.01 | ---- | ---- | ---- | ---- | ---- |
Soapstone (see Silicates) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Sodium azide | 26628-22-8 | (( |
||||||
(as HN3) | ---- | ---- | ---- | ---- | ---- | 0.1 | 0.3 | X |
(as NaN3) | ---- | ---- | ---- | ---- | ---- | 0.1 | 0.3 | X |
Sodium bisulfite | 7631-90-5 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Sodium-2,
4-dichlorophenoxyethyl sulfate (see Crag herbicide) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Sodium fluoroacetate | 62-74-8 | ---- | 0.05 | ---- | 0.15 | ---- | ---- | X |
Sodium hydroxide | 1310-73-2 | ---- | ---- | ---- | ---- | ---- | 2.0 | ---- |
Sodium metabisulfite | 7681-57-4 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Starch | 9005-25-8 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Stibine | 7803-52-3 | 0.1 | 0.5 | ---- | ---- | ---- | ---- | ---- |
Stoddard solvent | 8052-41-3 | 100 | 525 | ---- | ---- | ---- | ---- | ---- |
Strychnine | 57-24-9 | ---- | 0.15 | ---- | ---- | ---- | ---- | ---- |
Styrene | 100-42-5 | 50 | 215 | 100 | 425 | ---- | ---- | ---- |
Subtilisins | 9014-01-1 | ---- | ---- | ---- | 0.00006 | ---- | ---- | ---- |
(60min.)
(( |
(( |
|||||||
Sucrose | 57-50-1 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Sulfotep (see TEDP) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | X |
Sulfur dioxide | 7446-09-5 | 2.0 | 5.0 | 5.0 | 13 | ---- | ---- | ---- |
Sulfur hexafluoride | 2551-62-4 | 1,000 | 6,000 | ---- | ---- | ---- | ---- | ---- |
Sulfuric acid | 7664-93-9 | ---- | 1.0 | ---- | ---- | ---- | ---- | ---- |
Sulfur monochloride | 10025-67-9 | ---- | ---- | ---- | ---- | 1.0 | 6.0 | ---- |
Sulfur pentafluoride | 5714-22-1 | ---- | ---- | ---- | ---- | 0.01 | 0.1 | ---- |
Sulfur tetrafluoride | 7783-60-0 | ---- | ---- | ---- | ---- | 0.1 | 0.4 | ---- |
Sulfuryl fluoride | 2699-79-8 | 5.0 | 20 | 10 | 40 | ---- | ---- | ---- |
Sulprofos | 35400-43-2 | ---- | 1.0 | ---- | ---- | ---- | ---- | ---- |
Systox (see Demeton) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
2, 4, 5-T | 93-76-5 | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Talc (see Silicates) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Tantalum
Metal and oxide dusts |
7440-25-7 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
TEDP (Sulfotep) | 3689-24-5 | ---- | 0.2 | ---- | ---- | ---- | ---- | X |
Tellurium and compounds (as Te) | 13494-80-9 | ---- | 0.1 | ---- | ---- | ---- | ---- | ---- |
Tellurium hexafluoride (as Te) | 7783-80-4 | 0.02 | 0.2 | ---- | ---- | ---- | ---- | ---- |
Temephos | 3383-96-8 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
TEPP | 107-49-3 | 0.004 | 0.05 | ---- | ---- | ---- | ---- | X |
Terphenyls | 26140-60-3 | ---- | ---- | ---- | ---- | 0.5 | 5.0 | ---- |
1, 1, 1, 2-Tetrachloro-2,
2-difluoroethane |
76-11-0 | 500 | 4,170 | ---- | ---- | ---- | ---- | ---- |
1, 1, 2, 2-Tetrachloro-1,
2-difluoroethane |
76-12-0 | 500 | 4,170 | ---- | ---- | ---- | ---- | ---- |
1, 1, 2, 2-Tetrachloroethane | 79-34-5 | 1.0 | 7.0 | ---- | ---- | ---- | ---- | X |
Tetrachloroethylene
(see Perchloroethylene) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Tetrachloromethane
(see Carbon tetrachloride) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Tetrachloronaphhalene | 1335-88-2 | ---- | 2.0 | ---- | ---- | ---- | ---- | X |
Tetraethyl lead (as Pb) | 78-00-2 | ---- | 0.075 | ---- | ---- | ---- | ---- | X |
Tetrahydrofuan | 109-99-9 | 200 | 590 | 250 | 735 | ---- | ---- | ---- |
Tetramethyl lead (as Pb) | 75-74-1 | ---- | 0.075 | ---- | ---- | ---- | ---- | X |
Tetramethyl succinonitrile | 3333-52-6 | 0.5 | 3.0 | ---- | ---- | ---- | ---- | X |
Tetranitromethane | 509-14-8 | 1.0 | 8.0 | ---- | ---- | ---- | ---- | ---- |
Tetrasodium pyrophosphate | 7722-88-5 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Tetryl (2, 4, 6-trinitrophenyl-
methylnitramine) |
479-45-8 | ---- | 1.5 | ---- | ---- | ---- | ---- | X |
Thallium (soluble compounds)
(as Tl) |
7440-28-0 | ---- | 0.1 | ---- | ---- | ---- | ---- | X |
4, 4-Thiobis
(6-tert-butyl-m-cresol) |
96-69-5 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Thioglycolic acid | 68-11-1 | 1.0 | 4.0 | ---- | ---- | ---- | ---- | X |
Thionyl chloride | 7719-09-7 | ---- | ---- | ---- | ---- | 1.0 | 5.0 | ---- |
Thiram
(see WAC 296-62-07519) |
137-26-8 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Tin (as Sn)
Inorganic compounds (except oxides) |
7440-31-5 | ---- | 2.0 | ---- | ---- | ---- | ---- | ---- |
Tin, Organic compounds (as Sn) | 7440-31-5 | ---- | 0.1 | ---- | ---- | ---- | ---- | X |
Tin Oxide (as Sn) | 21651-19-4 | ---- | 2.0 | ---- | ---- | ---- | ---- | ---- |
Titanium dioxide | 13463-67-7 | (( |
||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Toulene | 108-88-3 | 100 | 375 | 150 | 560 | ---- | ---- | ---- |
Toluene-2, 4-diisocyanate (TDI) | 584-84-9 | 0.005 | 0.04 | 0.02 | 0.15 | ---- | ---- | ---- |
m-Toluidine | 108-44-1 | 2.0 | 9.0 | ---- | ---- | ---- | ---- | X |
o-Toluidine | 95-53-4 | 2.0 | 9.0 | ---- | ---- | ---- | ---- | X |
p-Toluidine | 106-49-0 | 2.0 | 9.0 | ---- | ---- | ---- | ---- | X |
Toxaphene
(see Chlorinated camphene) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Tremolite (see Silicates) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Tributyl phosphate | 126-73-8 | 0.2 | 2.5 | ---- | ---- | ---- | ---- | ---- |
Trichloroacetic acid | 76-03-9 | 1.0 | 7.0 | ---- | ---- | ---- | ---- | ---- |
1, 2, 4-Trichlorobenzene | 120-82-1 | ---- | ---- | ---- | ---- | 5.0 | 40 | ---- |
1, 1, 1-Trichloroethane
(see Methyl chloroform) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
1, 1, 2-Trichloroethane | 79-00-5 | 10 | 45 | ---- | ---- | ---- | ---- | ---- |
Trichloroethylene | 79-01-6 | 50 | 270 | 200 | 1,080 | ---- | ---- | ---- |
Trichlorofluoromethane | 75-69-4 | ---- | ---- | ---- | ---- | 1,000 | 5,600 | ---- |
Trichloromethane
(see Chloroform) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Trichloronaphthalene | 1321-65-9 | ---- | 5.0 | ---- | ---- | ---- | ---- | X |
1, 2, 3-Trichloropropane | 96-18-4 | 10 | 60 | ---- | ---- | ---- | ---- | X |
1, 1, 2-Trichloro-1, 2,
2-trifluoroethane |
76-13-1 | 1,000 | 7,600 | 1,250 | 9,500 | ---- | ---- | ---- |
Tricyclohexyltin hydroxide
(see Cyhexatin) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Triethylamine | 121-44-8 | 10 | 40 | 15 | 60 | ---- | ---- | ---- |
Trifluorobromomethane | 75-63-8 | 1,000 | 6,100 | ---- | ---- | ---- | ---- | ---- |
Trimellitic anhydride | 552-30-7 | 0.005 | 0.04 | ---- | ---- | ---- | ---- | ---- |
Trimethylamine | 75-50-3 | 10 | 24 | 15 | 36 | ---- | ---- | ---- |
Trimethyl benzene | 25551-13-7 | 25 | 125 | ---- | ---- | ---- | ---- | ---- |
Trimethyl phosphite | 121-45-9 | 2.0 | 10 | ---- | ---- | ---- | ---- | ---- |
2, 4, 6-Trinitrophenol
(see Picric acid) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
2, 4, 6-Trinitrophenyl-
methylnitramine (see Tetryl) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
2, 4, 6-Trinitrotoluene (TNT) | 118-96-7 | ---- | 0.5 | ---- | ---- | ---- | ---- | X |
Triorthocresyl phosphate | 78-30-8 | ---- | 0.1 | ---- | ---- | ---- | ---- | X |
Triphenyl amine | 603-34-9 | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Triphenyl phosphate | 115-86-6 | ---- | 3.0 | ---- | ---- | ---- | ---- | ---- |
Tungsten (as W) | 7440-33-7 | (( |
||||||
Soluble compounds | ---- | ---- | 1.0 | ---- | 3.0 | ---- | ---- | ---- |
Insoluble compounds | ---- | ---- | 5.0 | ---- | 10 | ---- | ---- | ---- |
Turpentine | 8006-64-2 | 100 | 560 | ---- | ---- | ---- | ---- | ---- |
Uranium (as U) | 7440-61-1 | (( |
||||||
Soluble compounds | ---- | ---- | 0.05 | ---- | ---- | ---- | ---- | ---- |
Insoluble compounds | ---- | ---- | 0.2 | ---- | 0.6 | ---- | ---- | ---- |
n-Valeraldehyde | 110-62-3 | 50 | 175 | ---- | ---- | ---- | ---- | ---- |
Vanadium (as V2O5) | 1314-62-1 | ---- | 0.05 | ---- | ---- | ---- | ---- | ---- |
Respirable dust and fume | ||||||||
Vegetable oil mist | (( |
|||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Vinyl acetate | 108-05-1 | 10 | 30 | 20 | 60 | ---- | ---- | ---- |
Vinyl benzene (see Styrene) | ---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Vinyl bromide | 593-60-2 | 5.0 | 20 | ---- | ---- | ---- | ---- | ---- |
Vinyl chloride
(see WAC 296-62-07329) |
75-01-4 | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Vinyl cyanide
(see Acrylonitrile) |
---- | ---- | ---- | ---- | ---- | ---- | ---- | ---- |
Vinyl cyclohexene dioxide | 106-87-6 | 10 | 60 | ---- | ---- | ---- | ---- | X |
Vinyl toluene | 25013-15-4 | 50 | 240 | ---- | ---- | ---- | ---- | ---- |
Vinylidene chloride
(1, 1-Dichloroethylene) |
75-35-4 | 1.0 | 4.0 | ---- | ---- | ---- | ---- | ---- |
VM & P Naphtha | 8032-32-4 | 300 | 1,350 | 400 | 1,800 | ---- | ---- | ---- |
Warfarin | 81-81-2 | ---- | 0.1 | ---- | ---- | ---- | ---- | ---- |
Welding fumes (( (total particulate) |
---- | ---- | 5.0 | ---- | ---- | ---- | ---- | ---- |
Wood dust(( |
||||||||
Nonallergenic;
All soft woods and hard woods except allergenics |
---- | ---- | 5.0 | ---- | 10 | ---- | ---- | ---- |
Allergenics; (e.g. cedar,
mahogany and teak) |
---- | ---- | 2.5 | ---- | ---- | ---- | ---- | ---- |
Xylenes (Xylol)
(o-, m-, p-isomers) |
1330-20-7 | 100 | 435 | 150 | 655 | ---- | ---- | ---- |
m-Xylene alpha, alpha-diamine | 1477-55-0 | ---- | ---- | ---- | ---- | ---- | 0.1 | X |
Xylidine | 1300-73-8 | 2.0 | 10 | ---- | ---- | ---- | ---- | X |
Yttrium | 7440-65-5 | ---- | 1.0 | ---- | ---- | ---- | ---- | ---- |
Zinc chloride fume | 7646-85-7 | ---- | 1.0 | ---- | 2.0 | ---- | ---- | ---- |
Zinc chromate (as Cr03) | Varies (( |
---- | 0.05 | ---- | ---- | ---- | 0.1 | ---- |
Zinc oxide | 1314-13-2 | |||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Zinc oxide fume | 1314-13-2 | ---- | 5.0 | ---- | 10 | ---- | ---- | ---- |
Zinc stearate | 557-05-1 | |||||||
Total dust | ---- | ---- | 10 | ---- | ---- | ---- | ---- | ---- |
Respirable fraction | ---- | ---- | 5.0k | ---- | ---- | ---- | ---- | ---- |
Zirconium compounds (as Zr) | 7440-67-2 | ---- | 5.0 | ---- | 10 | ---- | ---- | ---- |
Notes: a((/)) Parts of vapor or gas per million parts of contaminated air by volume at 25((')) degrees C and 760 mm((.)) Hg((.))
pressure (torr((.))).
b((/)) Milligrams of substance per cubic meter of air. When a numerical entry for a substance is in the mg/m3 column and
not in the ppm column, then the number in the mg/m3 column is exact. When numerical entries for a substance are
in both the ppm and mg/m3 columns, then the number in the ppm column is exact and the number in the mg/m3
column may be rounded off.
c((/)) Duration is for 15 minutes, unless otherwise noted.
d((/)) The final benzene standard in WAC 296-62-07523 applies to all occupational exposures to benzene except some sub-segments of industry where exposures are consistently under the action level (i.e., distribution and sale of fuels,
sealed containers and pipelines, coke production, oil and gas drilling and production, natural gas processing, and the
percentage exclusion for liquid mixtures).
e((/)) This 8-hour TWA applies to respirable dust as measured by a vertical elutriator cotton dust sampler or equivalent
instrument. The time-weighted average applies to the cotton waste processing operations of waste recycling (sorting,
blending, cleaning, and willowing) and garretting. See also WAC 296-62-14533 for cotton dust limits applicable to
other sectors.
f((/)) As determined from breathing-zone air samples.
g((/ Total dust formula for Silica (as quartz) is:
30mg/m3
% SiO2 + 3
h/)) Both concentration and percent quartz for the application of this limit are to be determined from the fraction passing
a size-selector with the following characterstics:
Aerodynamic diameter
(unit_density_sphere) |
Percent_passing_selector |
(( |
|
1 | 97 |
2 | 91 |
3 | 74 |
4 | 50 |
5 | 30 |
6 | 17 |
7 | 9 |
8 | 5 |
10 | 1 |
((Notes: i/)) h The CAS number is for information only. Enforcement is based on the substance name. For an entry covering more
than one metal compound measured as the metal, the CAS number for the metal is given -- not CAS numbers for the
individual compounds.
((j/)) i Compliance with the subtilisins PEL is assessed by sampling with a high volume sampler (600-800 liters per minute)
for at least 60 minutes.
((m/)) j Sampling for the carbon monoxide ceiling shall be averaged over 5 minutes but an instantaneous reading over 1500
ppm shall not be exceeded.
k The concentration of respirable particulate for the application of this limit is determined from the fraction passing a size-selector with the following characteristics.
Aerodynamic diameter
(unit density sphere) |
Percent passing selector |
1 | 97 |
2 | 91 |
3 | 74 |
4 | 50 |
5 | 30 |
6 | 17 |
7 | 9 |
8 | 5 |
10 | 1 |
[Statutory Authority: RCW 49.17.040, [49.17.]050 and [49.17.]060. 97-19-014, § 296-62-07515, filed 9/5/97, effective 11/5/97. Statutory Authority: Chapter 49.17 RCW. 96-17-056, § 296-62-07515, filed 8/20/96, effective 10/15/96; 93-01-067 (Order 92-15), § 296-62-07515, filed 12/11/92, effective 1/15/93; 91-11-070 (Order 91-01), § 296-62-07515, filed 5/20/91, effective 6/20/91; 90-03-029 (Order 89-20), § 296-62-07515, filed 1/11/90, effective 2/26/90; 89-15-002 (Order 89-06), § 296-62-07515, filed 7/6/89, effective 8/7/89; 88-14-108 (Order 88-11), § 296-62-07515, filed 7/6/88; 87-24-051 (Order 87-24), § 296-62-07515, filed 11/30/87. Statutory Authority: RCW 49.17.040 and 49.17.050. 86-16-009 (Order 86-28), § 296-62-07515, filed 7/25/86; 85-01-022 (Order 84-24), § 296-62-07515, filed 12/11/84; 82-13-045 (Order 82-22), § 296-62-07515, filed 6/11/82. Statutory Authority: RCW 49.17.040, 49.17.050 and 49.17.240. 81-16-015 (Order 81-20), § 296-62-07515, filed 7/27/81; 80-11-010 (Order 80-14), § 296-62-07515, filed 8/8/80. Statutory Authority: RCW 49.17.040, 49.17.150 and 49.17.240. 79-08-115 (Order 79-9), § 296-62-07515, filed 7/31/79; Order 73-3, § 296-62-07515, filed 5/7/73.]